Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case Study

The increase in waste has motivated the adoption of the circular economy concept, which assumes particular relevance in the case of plastic materials. This has led to research of new possibilities for recycling plastics after their end-of-life. To achieve this goal, it is fundamental to understand h...

Full description

Bibliographic Details
Main Authors: André A. Costa, Pedro G. Martinho, Fátima M. Barreiros
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Recycling
Subjects:
Online Access:https://www.mdpi.com/2313-4321/8/1/12
_version_ 1797618515716341760
author André A. Costa
Pedro G. Martinho
Fátima M. Barreiros
author_facet André A. Costa
Pedro G. Martinho
Fátima M. Barreiros
author_sort André A. Costa
collection DOAJ
description The increase in waste has motivated the adoption of the circular economy concept, which assumes particular relevance in the case of plastic materials. This has led to research of new possibilities for recycling plastics after their end-of-life. To achieve this goal, it is fundamental to understand how the materials’ properties change after recycling. This study aims to evaluate the thermal and mechanical properties of recycled plastics, namely polycarbonate (PC), polystyrene (PS), glass fibre-reinforced polyamide 6 (PA6-GF30), and polyethylene terephthalate (PET). With this purpose, injected samples were mechanically recycled twice and compared through thermal and mechanical tests, such as differential scanning calorimetry, hardness, tensile strength, and the melt flow rate. The results show that the amorphous materials used do not suffer significant changes in their properties but exhibit changes in their optical characteristics. The semicrystalline ones present some modifications. PET is the material that suffers the biggest changes, both in its flowability and mechanical properties. This work demonstrates that the mechanical recycling process may be an interesting possibility for recycling depending on the desired quality of final products, allowing for some materials to maintain comparable thermal and mechanical properties after going through the recycling process.
first_indexed 2024-03-11T08:13:49Z
format Article
id doaj.art-6d13fb87d7c44330ad8d7d27b2e458f7
institution Directory Open Access Journal
issn 2313-4321
language English
last_indexed 2024-03-11T08:13:49Z
publishDate 2023-01-01
publisher MDPI AG
record_format Article
series Recycling
spelling doaj.art-6d13fb87d7c44330ad8d7d27b2e458f72023-11-16T22:58:21ZengMDPI AGRecycling2313-43212023-01-01811210.3390/recycling8010012Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case StudyAndré A. Costa0Pedro G. Martinho1Fátima M. Barreiros2School of Technology and Management, Polytechnic of Leiria, 2411-901 Leiria, PortugalSchool of Technology and Management, Polytechnic of Leiria, 2411-901 Leiria, PortugalSchool of Technology and Management, Polytechnic of Leiria, 2411-901 Leiria, PortugalThe increase in waste has motivated the adoption of the circular economy concept, which assumes particular relevance in the case of plastic materials. This has led to research of new possibilities for recycling plastics after their end-of-life. To achieve this goal, it is fundamental to understand how the materials’ properties change after recycling. This study aims to evaluate the thermal and mechanical properties of recycled plastics, namely polycarbonate (PC), polystyrene (PS), glass fibre-reinforced polyamide 6 (PA6-GF30), and polyethylene terephthalate (PET). With this purpose, injected samples were mechanically recycled twice and compared through thermal and mechanical tests, such as differential scanning calorimetry, hardness, tensile strength, and the melt flow rate. The results show that the amorphous materials used do not suffer significant changes in their properties but exhibit changes in their optical characteristics. The semicrystalline ones present some modifications. PET is the material that suffers the biggest changes, both in its flowability and mechanical properties. This work demonstrates that the mechanical recycling process may be an interesting possibility for recycling depending on the desired quality of final products, allowing for some materials to maintain comparable thermal and mechanical properties after going through the recycling process.https://www.mdpi.com/2313-4321/8/1/12injection mouldingthermal and mechanical propertiesmechanical recyclingpolycarbonate (PC)polystyrene (PS)glass fibre-reinforced polyamide 6 (PA6-GF30)
spellingShingle André A. Costa
Pedro G. Martinho
Fátima M. Barreiros
Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case Study
Recycling
injection moulding
thermal and mechanical properties
mechanical recycling
polycarbonate (PC)
polystyrene (PS)
glass fibre-reinforced polyamide 6 (PA6-GF30)
title Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case Study
title_full Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case Study
title_fullStr Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case Study
title_full_unstemmed Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case Study
title_short Comparison between the Mechanical Recycling Behaviour of Amorphous and Semicrystalline Polymers: A Case Study
title_sort comparison between the mechanical recycling behaviour of amorphous and semicrystalline polymers a case study
topic injection moulding
thermal and mechanical properties
mechanical recycling
polycarbonate (PC)
polystyrene (PS)
glass fibre-reinforced polyamide 6 (PA6-GF30)
url https://www.mdpi.com/2313-4321/8/1/12
work_keys_str_mv AT andreacosta comparisonbetweenthemechanicalrecyclingbehaviourofamorphousandsemicrystallinepolymersacasestudy
AT pedrogmartinho comparisonbetweenthemechanicalrecyclingbehaviourofamorphousandsemicrystallinepolymersacasestudy
AT fatimambarreiros comparisonbetweenthemechanicalrecyclingbehaviourofamorphousandsemicrystallinepolymersacasestudy