(Carbonyl-1κC)bis[2,3(η5)-cyclopentadienyl][μ3-(S-methyl trithiocarbonato)methylidyne-1:2:3κ4C,S′′:C:C](triphenylphosphine-1κP)(μ3-sulfido-1:2:3κ3S)dicobalt(II)iron(II) trifluoromethanesulfonate

(Carbonyl-1κC)bis[2,3(η5)-cyclopentadienyl][μ3-(S-methyl trithiocarbonato)methylidyne-1:2:3κ4C,S′′:C:C](triphenylphosphine-1κP)(μ3-sulfido-1:2:3κ3S)dicobalt(II)iron(II) trifluoromethanesulfonate

The asymmetric unit of the title compound, [FeCo2(C5H5)2(C3H3S3)S(C18H15P)(CO)]CF3SO3, consists of a triangular irondicobalt cluster cation and a trifluoromethanesulfonate anion. In the cation, the FeCo2 triangle is symmetrically capped on one face by an S atom and on the other by a C atom linked to...

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Bibliographic Details
Main Authors: Jim Simpson, Anthony J. Palmer, C. John McAdam, Anthony R. Manning
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808008970

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