Influence of ceramic particle features on the thermal behavior of PPO-matrix composites

Thermoplastic poly(phenylene oxide) (PPO)-matrix composites were prepared and characterized in order to evaluate the effect of different ceramic fillers on the thermal and combustion behavior of the matrix. In particular, ceramic particles having three different shapes were exploited as fillers, par...

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Main Authors: Lombardi Mariangela, Fino Paolo, Montanaro Laura
Format: Article
Language:English
Published: De Gruyter 2014-01-01
Series:Science and Engineering of Composite Materials
Subjects:
Online Access:https://doi.org/10.1515/secm-2012-0139
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author Lombardi Mariangela
Fino Paolo
Montanaro Laura
author_facet Lombardi Mariangela
Fino Paolo
Montanaro Laura
author_sort Lombardi Mariangela
collection DOAJ
description Thermoplastic poly(phenylene oxide) (PPO)-matrix composites were prepared and characterized in order to evaluate the effect of different ceramic fillers on the thermal and combustion behavior of the matrix. In particular, ceramic particles having three different shapes were exploited as fillers, particles showing a platelet-like, a needle-like or an equiaxial morphology. The composite materials were produced through a melt blending method, which yielded a homogeneous distribution of the ceramic particles in the organic matrix. It was demonstrated that the presence of the inorganic particles influenced the temperature range in which the degradation processes of the polymer occurred. In addition, the three fillers modified the thermal behavior of PPO differently in terms of enthalpy. Finally, the presence of the filler induced a change in combustion behavior of the polymeric matrix; in particular, sepiolite was able to increase the charring ability of the PPO/polystyrene blend with the development of a visible carbonaceous layer.
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spelling doaj.art-6d7d1b38269d4785b0d91e56caf9ffcd2022-12-21T22:40:54ZengDe GruyterScience and Engineering of Composite Materials0792-12332191-03592014-01-01211232810.1515/secm-2012-0139Influence of ceramic particle features on the thermal behavior of PPO-matrix compositesLombardi Mariangela0Fino Paolo1Montanaro Laura2Department of Applied Science and Technology, Politecnico di Torino, INSTM RU Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, INSTM RU Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, ItalyDepartment of Applied Science and Technology, Politecnico di Torino, INSTM RU Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin, ItalyThermoplastic poly(phenylene oxide) (PPO)-matrix composites were prepared and characterized in order to evaluate the effect of different ceramic fillers on the thermal and combustion behavior of the matrix. In particular, ceramic particles having three different shapes were exploited as fillers, particles showing a platelet-like, a needle-like or an equiaxial morphology. The composite materials were produced through a melt blending method, which yielded a homogeneous distribution of the ceramic particles in the organic matrix. It was demonstrated that the presence of the inorganic particles influenced the temperature range in which the degradation processes of the polymer occurred. In addition, the three fillers modified the thermal behavior of PPO differently in terms of enthalpy. Finally, the presence of the filler induced a change in combustion behavior of the polymeric matrix; in particular, sepiolite was able to increase the charring ability of the PPO/polystyrene blend with the development of a visible carbonaceous layer.https://doi.org/10.1515/secm-2012-0139ceramic fillerpolymer-matrix composites (pmcs)thermal propertiesthermoplastic resin
spellingShingle Lombardi Mariangela
Fino Paolo
Montanaro Laura
Influence of ceramic particle features on the thermal behavior of PPO-matrix composites
Science and Engineering of Composite Materials
ceramic filler
polymer-matrix composites (pmcs)
thermal properties
thermoplastic resin
title Influence of ceramic particle features on the thermal behavior of PPO-matrix composites
title_full Influence of ceramic particle features on the thermal behavior of PPO-matrix composites
title_fullStr Influence of ceramic particle features on the thermal behavior of PPO-matrix composites
title_full_unstemmed Influence of ceramic particle features on the thermal behavior of PPO-matrix composites
title_short Influence of ceramic particle features on the thermal behavior of PPO-matrix composites
title_sort influence of ceramic particle features on the thermal behavior of ppo matrix composites
topic ceramic filler
polymer-matrix composites (pmcs)
thermal properties
thermoplastic resin
url https://doi.org/10.1515/secm-2012-0139
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AT montanarolaura influenceofceramicparticlefeaturesonthethermalbehaviorofppomatrixcomposites