Summary: | Porous materials have superior electrochemical performance owing to its their structure, which could increase the specific and contact area with the electrode. The spinel Li4Mn5O12 has a three-dimensional tunnel structure for a better diffusion path, which has the advantage of lithium ion insertion and extraction in the framework. However, multi-space spherical materials with single morphologies are rarely studied. In this work, waxberry-like and raspberry-like nanospheres for Li4Mn5O12 have been fabricated by the wet chemistry and solid-state methods for the first time. The diameter of a single waxberry- and raspberry-like nanosphere is about 1 μm and 600 nm, respectively. The specific capacitance of Li4Mn5O12 was 535 mF cm−2 and 147.25 F g−1 at the scan rate of 2 mV s−1, and the energy density was 110.7 Wh kg−1, remaining at 70% after 5000th charge-discharge cycles. Compared with raspberry-like nanosphere Li4Mn5O12, the waxberry-like nanoporous spinel Li4Mn5O12 shows the better electrochemical performance and stability; furthermore, these electrochemical performances have been improved greatly compared to the previous studies. All these results indicate that the waxberry-like nanoporous spinel Li4Mn5O12 could provide a potential application in high performance supercapacitors.
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