Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base
This work describes an uncommon new case of imine hydrolysis, leading to the formation of a carboxylate group. The conditions of the media that favor this conversion, which seem to be mediated by the presence of Dy<sup>III</sup>, are analyzed. The process brings about the formation of a...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-11-01
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| Series: | Chemistry Proceedings |
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| Online Access: | https://www.mdpi.com/2673-4583/8/1/36 |
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| author | Julio Corredoira-Vázquez Cristina González-Barreira Ana M. García Deibe Jesús Sanmartín-Matalobos Matilde Fondo |
| author_facet | Julio Corredoira-Vázquez Cristina González-Barreira Ana M. García Deibe Jesús Sanmartín-Matalobos Matilde Fondo |
| author_sort | Julio Corredoira-Vázquez |
| collection | DOAJ |
| description | This work describes an uncommon new case of imine hydrolysis, leading to the formation of a carboxylate group. The conditions of the media that favor this conversion, which seem to be mediated by the presence of Dy<sup>III</sup>, are analyzed. The process brings about the formation of a dysprosium complex of formula {[(DyL<sub>2</sub>)<sub>2</sub>Na<sub>2</sub>(H<sub>2</sub>O)<sub>8</sub>][Et<sub>3</sub>NH]<sub>2</sub>[DyL<sub>2</sub>]<sub>2</sub>}·14H<sub>2</sub>O (<b>1</b>). Single X-ray characterization of the final product is reported. |
| first_indexed | 2024-03-11T06:46:39Z |
| format | Article |
| id | doaj.art-6d9a4ebc8c0849f0bbb2441acbba884e |
| institution | Directory Open Access Journal |
| issn | 2673-4583 |
| language | English |
| last_indexed | 2024-03-11T06:46:39Z |
| publishDate | 2021-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Chemistry Proceedings |
| spelling | doaj.art-6d9a4ebc8c0849f0bbb2441acbba884e2023-11-17T10:18:32ZengMDPI AGChemistry Proceedings2673-45832021-11-01813610.3390/ecsoc-25-11740Dysprosium(III)-Mediated Carboxylate Formation from a Schiff BaseJulio Corredoira-Vázquez0Cristina González-Barreira1Ana M. García Deibe2Jesús Sanmartín-Matalobos3Matilde Fondo4Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainDepartamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainDepartamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainDepartamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainDepartamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, SpainThis work describes an uncommon new case of imine hydrolysis, leading to the formation of a carboxylate group. The conditions of the media that favor this conversion, which seem to be mediated by the presence of Dy<sup>III</sup>, are analyzed. The process brings about the formation of a dysprosium complex of formula {[(DyL<sub>2</sub>)<sub>2</sub>Na<sub>2</sub>(H<sub>2</sub>O)<sub>8</sub>][Et<sub>3</sub>NH]<sub>2</sub>[DyL<sub>2</sub>]<sub>2</sub>}·14H<sub>2</sub>O (<b>1</b>). Single X-ray characterization of the final product is reported.https://www.mdpi.com/2673-4583/8/1/36Schiff basecarboxylatehydrolysisDy<sup>III</sup> |
| spellingShingle | Julio Corredoira-Vázquez Cristina González-Barreira Ana M. García Deibe Jesús Sanmartín-Matalobos Matilde Fondo Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base Chemistry Proceedings Schiff base carboxylate hydrolysis Dy<sup>III</sup> |
| title | Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base |
| title_full | Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base |
| title_fullStr | Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base |
| title_full_unstemmed | Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base |
| title_short | Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base |
| title_sort | dysprosium iii mediated carboxylate formation from a schiff base |
| topic | Schiff base carboxylate hydrolysis Dy<sup>III</sup> |
| url | https://www.mdpi.com/2673-4583/8/1/36 |
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