Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate

The triclinic unit cell of the title compound, [Ni(C3H4N2)2(H2O)4](C10H6O6S2), contains one centrosymmetric cation and one centrosymmetric anion. In the cation, the NiII ion is six-coordinated by two imidazole ligands [Ni—N = 2.0568 (14) Å] and four water molec...

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Main Authors: Dong-Sheng Deng, Ping Liu
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807067761
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author Dong-Sheng Deng
Ping Liu
author_facet Dong-Sheng Deng
Ping Liu
author_sort Dong-Sheng Deng
collection DOAJ
description The triclinic unit cell of the title compound, [Ni(C3H4N2)2(H2O)4](C10H6O6S2), contains one centrosymmetric cation and one centrosymmetric anion. In the cation, the NiII ion is six-coordinated by two imidazole ligands [Ni—N = 2.0568 (14) Å] and four water molecules [both independent Ni—O distances are 2.098 (1) Å] in a distorted octahedral geometry. Intermolecular O—H...O and N—H...O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.
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spelling doaj.art-6dabd1c2b2464ef1b262d908271ef6a02022-12-22T04:06:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m275m27510.1107/S1600536807067761Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonateDong-Sheng DengPing LiuThe triclinic unit cell of the title compound, [Ni(C3H4N2)2(H2O)4](C10H6O6S2), contains one centrosymmetric cation and one centrosymmetric anion. In the cation, the NiII ion is six-coordinated by two imidazole ligands [Ni—N = 2.0568 (14) Å] and four water molecules [both independent Ni—O distances are 2.098 (1) Å] in a distorted octahedral geometry. Intermolecular O—H...O and N—H...O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536807067761
spellingShingle Dong-Sheng Deng
Ping Liu
Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate
Acta Crystallographica Section E
title Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate
title_full Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate
title_fullStr Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate
title_full_unstemmed Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate
title_short Tetraaquadiimidazolenickel(II) naphthalene-1,5-disulfonate
title_sort tetraaquadiimidazolenickel ii naphthalene 1 5 disulfonate
url http://scripts.iucr.org/cgi-bin/paper?S1600536807067761
work_keys_str_mv AT dongshengdeng tetraaquadiimidazolenickeliinaphthalene15disulfonate
AT pingliu tetraaquadiimidazolenickeliinaphthalene15disulfonate