Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析)
研究枯草杆菌蛋白酶催化环糊精与癸二酸二乙烯酯在DMF有机溶剂中的区城选择性反应，产物结构经IR、1H NMR、13C NMR、MS和DSC分析证实为单-（2-O-乙烯癸二酰）-β环糊精；同时考察了三种不同的酶对反应的催化作用. 结果表明枯苹杆菌蛋白酶和Candida cylindracea脂肪酶对β-环糊精在C-2位仲羟基的酯交换反应显示很髙的选择性，而lipozyme固定化酶在此体系中没有催化活性....
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2004-09-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.2004.31.5.544-547 |
| _version_ | 1797236364664635392 |
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| author | XIAOYong-mei(肖咏梅) WUQi(吴起) WANGNa(王娜) LINXian-fu(林贤福) |
| author_facet | XIAOYong-mei(肖咏梅) WUQi(吴起) WANGNa(王娜) LINXian-fu(林贤福) |
| author_sort | XIAOYong-mei(肖咏梅) |
| collection | DOAJ |
| description | 研究枯草杆菌蛋白酶催化环糊精与癸二酸二乙烯酯在DMF有机溶剂中的区城选择性反应，产物结构经IR、1H NMR、13C NMR、MS和DSC分析证实为单-（2-O-乙烯癸二酰）-β环糊精；同时考察了三种不同的酶对反应的催化作用. 结果表明枯苹杆菌蛋白酶和Candida cylindracea脂肪酶对β-环糊精在C-2位仲羟基的酯交换反应显示很髙的选择性，而lipozyme固定化酶在此体系中没有催化活性. |
| first_indexed | 2024-04-24T17:02:41Z |
| format | Article |
| id | doaj.art-6dae9de4ed4a492f996aacce2b4aa0da |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T17:02:41Z |
| publishDate | 2004-09-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-6dae9de4ed4a492f996aacce2b4aa0da2024-03-29T01:58:21ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972004-09-01315544547zjup/1008-9497.2004.31.5.544-547Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析)XIAOYong-mei(肖咏梅)0WUQi(吴起)1WANGNa(王娜)2LINXian-fu(林贤福)3 1.Department of Chemistry, Zhejiang University, Hangzhou 310027, China( 1.浙江大学化学系，浙江 杭州 310027) 1.Department of Chemistry, Zhejiang University, Hangzhou 310027, China( 1.浙江大学化学系，浙江 杭州 310027) 1.Department of Chemistry, Zhejiang University, Hangzhou 310027, China( 1.浙江大学化学系，浙江 杭州 310027) 1.Department of Chemistry, Zhejiang University, Hangzhou 310027, China( 1.浙江大学化学系，浙江 杭州 310027)研究枯草杆菌蛋白酶催化环糊精与癸二酸二乙烯酯在DMF有机溶剂中的区城选择性反应，产物结构经IR、1H NMR、13C NMR、MS和DSC分析证实为单-（2-O-乙烯癸二酰）-β环糊精；同时考察了三种不同的酶对反应的催化作用. 结果表明枯苹杆菌蛋白酶和Candida cylindracea脂肪酶对β-环糊精在C-2位仲羟基的酯交换反应显示很髙的选择性，而lipozyme固定化酶在此体系中没有催化活性.https://doi.org/zjup/1008-9497.2004.31.5.544-547β-环糊精(β-cd)区域选择性仲羟基酰化酶促合成 |
| spellingShingle | XIAOYong-mei(肖咏梅) WUQi(吴起) WANGNa(王娜) LINXian-fu(林贤福) Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析) Zhejiang Daxue xuebao. Lixue ban β-环糊精(β-cd) 区域选择性 仲羟基酰化 酶促合成 |
| title | Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析) |
| title_full | Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析) |
| title_fullStr | Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析) |
| title_full_unstemmed | Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析) |
| title_short | Enzymatic synthesis and structure analysis of the monosubstituted derivative of β-cyclomaltoheptaose(单-（2-O-乙烯癸二酰）-β-泽环糊精的酶促合成和结构分析) |
| title_sort | enzymatic synthesis and structure analysis of the monosubstituted derivative of β cyclomaltoheptaose 单 2 o 乙烯癸二酰 β 泽环糊精的酶促合成和结构分析 |
| topic | β-环糊精(β-cd) 区域选择性 仲羟基酰化 酶促合成 |
| url | https://doi.org/zjup/1008-9497.2004.31.5.544-547 |
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