Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A Review

The presence of pharmaceutical products in the water cycle may cause harmful effects such as morphological, metabolic and sex alterations in aquatic organisms and the selection/development of organisms resistant to antimicrobial agents. The compounds’ stability and persistent character hinder their...

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Main Authors: Jessica Meijide, Patrick S. M. Dunlop, Marta Pazos, María Angeles Sanromán
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/11/1/85
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author Jessica Meijide
Patrick S. M. Dunlop
Marta Pazos
María Angeles Sanromán
author_facet Jessica Meijide
Patrick S. M. Dunlop
Marta Pazos
María Angeles Sanromán
author_sort Jessica Meijide
collection DOAJ
description The presence of pharmaceutical products in the water cycle may cause harmful effects such as morphological, metabolic and sex alterations in aquatic organisms and the selection/development of organisms resistant to antimicrobial agents. The compounds’ stability and persistent character hinder their elimination by conventional physico-chemical and biological treatments and thus, the development of new water purification technologies has drawn great attention from academic and industrial researchers. Recently, the electro-Fenton process has been demonstrated to be a viable alternative for the removal of these hazardous, recalcitrant compounds. This process occurs under the action of a suitable catalyst, with the majority of current scientific research focused on heterogeneous systems. A significant area of research centres working on the development of an appropriate catalyst able to overcome the operating limitations associated with the homogeneous process is concerned with the short service life and difficulty in the separation/recovery of the catalyst from polluted water. This review highlights a present trend in the use of different materials as electro-Fenton catalysts for pharmaceutical compound removal from aquatic environments. The main challenges facing these technologies revolve around the enhancement of performance, stability for long-term use, life-cycle analysis considerations and cost-effectiveness. Although treatment efficiency has improved significantly, ongoing research efforts need to deliver economic viability at a larger scale due to the high operating costs, primarily related to energy consumption.
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spelling doaj.art-6db8c68c9cb646b59182782d8c205a812023-12-03T12:36:35ZengMDPI AGCatalysts2073-43442021-01-011118510.3390/catal11010085Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A ReviewJessica Meijide0Patrick S. M. Dunlop1Marta Pazos2María Angeles Sanromán3CINTECX, Grupo de Bioingeniería y Procesos Sostenibles, Departamento de Ingeniería Química, Campus Lagoas-Marcosende, University of Vigo, 36310 Vigo, SpainNanotechnology and Integrated BioEngineering Centre, School of Engineering, University of Ulster, Newtownabbey BT37 0QB, UKCINTECX, Grupo de Bioingeniería y Procesos Sostenibles, Departamento de Ingeniería Química, Campus Lagoas-Marcosende, University of Vigo, 36310 Vigo, SpainCINTECX, Grupo de Bioingeniería y Procesos Sostenibles, Departamento de Ingeniería Química, Campus Lagoas-Marcosende, University of Vigo, 36310 Vigo, SpainThe presence of pharmaceutical products in the water cycle may cause harmful effects such as morphological, metabolic and sex alterations in aquatic organisms and the selection/development of organisms resistant to antimicrobial agents. The compounds’ stability and persistent character hinder their elimination by conventional physico-chemical and biological treatments and thus, the development of new water purification technologies has drawn great attention from academic and industrial researchers. Recently, the electro-Fenton process has been demonstrated to be a viable alternative for the removal of these hazardous, recalcitrant compounds. This process occurs under the action of a suitable catalyst, with the majority of current scientific research focused on heterogeneous systems. A significant area of research centres working on the development of an appropriate catalyst able to overcome the operating limitations associated with the homogeneous process is concerned with the short service life and difficulty in the separation/recovery of the catalyst from polluted water. This review highlights a present trend in the use of different materials as electro-Fenton catalysts for pharmaceutical compound removal from aquatic environments. The main challenges facing these technologies revolve around the enhancement of performance, stability for long-term use, life-cycle analysis considerations and cost-effectiveness. Although treatment efficiency has improved significantly, ongoing research efforts need to deliver economic viability at a larger scale due to the high operating costs, primarily related to energy consumption.https://www.mdpi.com/2073-4344/11/1/85electro-Fentonheterogeneous catalystpharmaceuticalsaqueous solution
spellingShingle Jessica Meijide
Patrick S. M. Dunlop
Marta Pazos
María Angeles Sanromán
Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A Review
Catalysts
electro-Fenton
heterogeneous catalyst
pharmaceuticals
aqueous solution
title Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A Review
title_full Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A Review
title_fullStr Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A Review
title_full_unstemmed Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A Review
title_short Heterogeneous Electro-Fenton as “Green” Technology for Pharmaceutical Removal: A Review
title_sort heterogeneous electro fenton as green technology for pharmaceutical removal a review
topic electro-Fenton
heterogeneous catalyst
pharmaceuticals
aqueous solution
url https://www.mdpi.com/2073-4344/11/1/85
work_keys_str_mv AT jessicameijide heterogeneouselectrofentonasgreentechnologyforpharmaceuticalremovalareview
AT patricksmdunlop heterogeneouselectrofentonasgreentechnologyforpharmaceuticalremovalareview
AT martapazos heterogeneouselectrofentonasgreentechnologyforpharmaceuticalremovalareview
AT mariaangelessanroman heterogeneouselectrofentonasgreentechnologyforpharmaceuticalremovalareview