Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives

Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives

This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported.

Bibliographic Details
Main Authors: Gareth J. Rowlands, Richard J. Seacome
Format: Article
Language:English
Published: Beilstein-Institut 2009-03-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
heterocycle
[2.2]paracyclophane
resolution
sulfur
Online Access:https://doi.org/10.3762/bjoc.5.9

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