(Z)-2-(2-Oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamide

In the title compound, C15H12N4OS, the dihedral angle between the nine-membered indolin-2-one ring system and the phenyl ring is 2.72 (7)°. Intramolecular cyclic N—H...O and C—H...S hydrogen-bonding interactions [graph set S(6)] are present, as...

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Bibliographic Details
Main Authors: Amna Qasem Ali, Naser Eltaher Eltayeb, Siang Guan Teoh, Abdussalam Salhin, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681200400X
Description
Summary:In the title compound, C15H12N4OS, the dihedral angle between the nine-membered indolin-2-one ring system and the phenyl ring is 2.72 (7)°. Intramolecular cyclic N—H...O and C—H...S hydrogen-bonding interactions [graph set S(6)] are present, as are weak N—H...N interactions [graph set S(5)]. In the crystal, molecules form centrosymmetric cyclic dimers through pairs of N—H...O hydrogen bonds [graph set R22(8)] and these are extended by C—H...S interactions. The crystal structure also features weak C—H...π interactions.
ISSN:1600-5368