Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides
The hydrogenolysis of glycerol was performed over a Pt/C catalyst in combination with several alkali metal hydroxides and their salts. LiOH was found to be an effective promoter for the selective hydrogenolysis of glycerol to 1,2-propanediol. Hydroxyl ions are the main factor to promote the reaction...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2016-01-01
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| Series: | Open Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/chem-2016-0030 |
| _version_ | 1818353759733940224 |
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| author | Feng Jian Xiong Wei Ding Hao He Bai |
| author_facet | Feng Jian Xiong Wei Ding Hao He Bai |
| author_sort | Feng Jian |
| collection | DOAJ |
| description | The hydrogenolysis of glycerol was performed over a Pt/C catalyst in combination with several alkali metal hydroxides and their salts. LiOH was found to be an effective promoter for the selective hydrogenolysis of glycerol to 1,2-propanediol. Hydroxyl ions are the main factor to promote the reaction process by dehydration of the glyceraldehyde intermediate. Lithium ions play a role in assisting the dehydrogenation of glycerol to glyceraldehyde, because they have the right size to coordinate with the alkoxide species. A possible surface reaction mechanism involving the participation of lithium ions was proposed to account for the results obtained in the study. |
| first_indexed | 2024-12-13T19:14:38Z |
| format | Article |
| id | doaj.art-6dccd559ab12420f98062e780299ec92 |
| institution | Directory Open Access Journal |
| issn | 2391-5420 |
| language | English |
| last_indexed | 2024-12-13T19:14:38Z |
| publishDate | 2016-01-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Open Chemistry |
| spelling | doaj.art-6dccd559ab12420f98062e780299ec922022-12-21T23:34:18ZengDe GruyterOpen Chemistry2391-54202016-01-0114127928610.1515/chem-2016-0030chem-2016-0030Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxidesFeng Jian0Xiong Wei1Ding Hao2He Bai3College of Chemistry and Chemical Engineering, Chongqing University of Science & Technology, Chongqing 401331, ChinaCollege of Chemistry and Chemical Engineering, Chongqing University of Science & Technology, Chongqing 401331, ChinaCollege of Chemistry and Chemical Engineering, Chongqing University of Science & Technology, Chongqing 401331, ChinaCollege of Chemistry and Chemical Engineering, Chongqing University of Science & Technology, Chongqing 401331, ChinaThe hydrogenolysis of glycerol was performed over a Pt/C catalyst in combination with several alkali metal hydroxides and their salts. LiOH was found to be an effective promoter for the selective hydrogenolysis of glycerol to 1,2-propanediol. Hydroxyl ions are the main factor to promote the reaction process by dehydration of the glyceraldehyde intermediate. Lithium ions play a role in assisting the dehydrogenation of glycerol to glyceraldehyde, because they have the right size to coordinate with the alkoxide species. A possible surface reaction mechanism involving the participation of lithium ions was proposed to account for the results obtained in the study.https://doi.org/10.1515/chem-2016-0030glycerolhydrogenolysisplatinum1,2-propanediollithium cation |
| spellingShingle | Feng Jian Xiong Wei Ding Hao He Bai Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides Open Chemistry glycerol hydrogenolysis platinum 1,2-propanediol lithium cation |
| title | Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides |
| title_full | Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides |
| title_fullStr | Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides |
| title_full_unstemmed | Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides |
| title_short | Hydrogenolysis of glycerol over Pt/C catalyst in combination with alkali metal hydroxides |
| title_sort | hydrogenolysis of glycerol over pt c catalyst in combination with alkali metal hydroxides |
| topic | glycerol hydrogenolysis platinum 1,2-propanediol lithium cation |
| url | https://doi.org/10.1515/chem-2016-0030 |
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