Two-Dimensional Hetero- to Homochiral Phase Transition from Dynamic Adsorption of Barbituric Acid Derivatives

Two-Dimensional Hetero- to Homochiral Phase Transition from Dynamic Adsorption of Barbituric Acid Derivatives

Barbituric acid derivative (TDPT) is an achiral molecule, and its adsorption on a surface results in two opposite enantiomerically oriented motifs, namely TDPT-S<sub>p</sub> and R<sub>p</sub>. Two types of building blocks can be formed; block I is enantiomer-pure and is built...

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Bibliographic Details
Main Authors: Fabien Silly, Changzhi Dong, François Maurel, Xiaonan Sun
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Nanomaterials
Subjects:
2D chiral
heterochiral
homochiral
enantiomer
self-assembly
hydrogen bond
Online Access:https://www.mdpi.com/2079-4991/13/16/2304

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