Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-Assembly

The room temperature deposition of self-assembling silica nanoparticles onto D-shaped optical fibres (“D-fibre”), drawn from milled preforms fabricated by modified chemical vapour deposition (MCVD), is studied. Vertical dip-and-withdraw produces tapered layers, with one end thicker (surface coverag...

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Main Authors: John Canning, Lucas Moura, Lachlan Lindoy, Kevin Cook, Maxwell J. Crossley, Yanhua Luo, Gang-Ding Peng, Lars Glavind, George Huyang, Masood Naqshbandi, Martin Kristensen, Cicero Martelli, Graham Town
Format: Article
Language:English
Published: MDPI AG 2014-03-01
Series:Materials
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Online Access:http://www.mdpi.com/1996-1944/7/3/2356
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author John Canning
Lucas Moura
Lachlan Lindoy
Kevin Cook
Maxwell J. Crossley
Yanhua Luo
Gang-Ding Peng
Lars Glavind
George Huyang
Masood Naqshbandi
Martin Kristensen
Cicero Martelli
Graham Town
author_facet John Canning
Lucas Moura
Lachlan Lindoy
Kevin Cook
Maxwell J. Crossley
Yanhua Luo
Gang-Ding Peng
Lars Glavind
George Huyang
Masood Naqshbandi
Martin Kristensen
Cicero Martelli
Graham Town
author_sort John Canning
collection DOAJ
description The room temperature deposition of self-assembling silica nanoparticles onto D-shaped optical fibres (“D-fibre”), drawn from milled preforms fabricated by modified chemical vapour deposition (MCVD), is studied. Vertical dip-and-withdraw produces tapered layers, with one end thicker (surface coverage >0.85) than the other, whilst horizontal dip-and-withdraw produces much more uniform layers over the core region. The propagation of induced fracturing over the core region during drying is overcome using a simple protrusion of the inner cladding. Thick coatings are discernible through thin film interference colouring, but thinner coatings require scanning electron microscopy (SEM) imaging. Here, we show that fluorescence imaging, using Rhodamine B, in this example, can provide some qualitative and speedy assessment of coverage.
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spelling doaj.art-6e08b98d379c4dff80591b0b4e0519002022-12-22T03:31:01ZengMDPI AGMaterials1996-19442014-03-01732356236910.3390/ma7032356ma7032356Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-AssemblyJohn Canning0Lucas Moura1Lachlan Lindoy2Kevin Cook3Maxwell J. Crossley4Yanhua Luo5Gang-Ding Peng6Lars Glavind7George Huyang8Masood Naqshbandi9Martin Kristensen10Cicero Martelli11Graham Town12interdisciplinary Photonics Laboratories (iPL), School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australiainterdisciplinary Photonics Laboratories (iPL), School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australiainterdisciplinary Photonics Laboratories (iPL), School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australiainterdisciplinary Photonics Laboratories (iPL), School of Chemistry, The University of Sydney, Sydney, NSW 2006, AustraliaSchool of Chemistry, The University of Sydney, Sydney, NSW 2006, AustraliaPhotonics & Optical Communications, School of Electrical Engineering and Telecommunications, The University of New South Wales, Sydney, NSW 2052, AustraliaPhotonics & Optical Communications, School of Electrical Engineering and Telecommunications, The University of New South Wales, Sydney, NSW 2052, AustraliaDepartment of Engineering, Finlandsgade 22, Aarhus University, Aarhus N 8200, Denmarkinterdisciplinary Photonics Laboratories (iPL), School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australiainterdisciplinary Photonics Laboratories (iPL), School of Chemistry, The University of Sydney, Sydney, NSW 2006, AustraliaDepartment of Engineering, Finlandsgade 22, Aarhus University, Aarhus N 8200, DenmarkGraduate School of Electrical Engineering and Applied Computer Science, Federal University of Technology-Paraná, Curitiba PR 80230-901, BrazilDepartment of Engineering, Macquarie University, Sydney, NSW 2109, AustraliaThe room temperature deposition of self-assembling silica nanoparticles onto D-shaped optical fibres (“D-fibre”), drawn from milled preforms fabricated by modified chemical vapour deposition (MCVD), is studied. Vertical dip-and-withdraw produces tapered layers, with one end thicker (surface coverage >0.85) than the other, whilst horizontal dip-and-withdraw produces much more uniform layers over the core region. The propagation of induced fracturing over the core region during drying is overcome using a simple protrusion of the inner cladding. Thick coatings are discernible through thin film interference colouring, but thinner coatings require scanning electron microscopy (SEM) imaging. Here, we show that fluorescence imaging, using Rhodamine B, in this example, can provide some qualitative and speedy assessment of coverage.http://www.mdpi.com/1996-1944/7/3/2356lab-in-a-fibrelab-on-fibrenanoparticlesbiochemicalself-assemblymicrofibersfiltersnanoreactionssensors
spellingShingle John Canning
Lucas Moura
Lachlan Lindoy
Kevin Cook
Maxwell J. Crossley
Yanhua Luo
Gang-Ding Peng
Lars Glavind
George Huyang
Masood Naqshbandi
Martin Kristensen
Cicero Martelli
Graham Town
Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-Assembly
Materials
lab-in-a-fibre
lab-on-fibre
nanoparticles
biochemical
self-assembly
microfibers
filters
nanoreactions
sensors
title Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-Assembly
title_full Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-Assembly
title_fullStr Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-Assembly
title_full_unstemmed Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-Assembly
title_short Fabricating Nanoporous Silica Structure on D-Fibres through Room Temperature Self-Assembly
title_sort fabricating nanoporous silica structure on d fibres through room temperature self assembly
topic lab-in-a-fibre
lab-on-fibre
nanoparticles
biochemical
self-assembly
microfibers
filters
nanoreactions
sensors
url http://www.mdpi.com/1996-1944/7/3/2356
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