Surface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performance

The photovoltaic performance of a hybrid ZnO/P3HT heterojunction was improved by modifying the device surface with the MK-2 dye. This organic dye enhanced the compatibility between the polymer and the metal oxide, increased the exciton separation efficiency, and improved the molecular ordering in th...

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Main Authors: Yu Jin Kim, Tae Kyu An, Seung-Jeong Oh, Dae Sung Chung, Chan Eon Park
Format: Article
Language:English
Published: AIP Publishing LLC 2014-07-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4886217
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author Yu Jin Kim
Tae Kyu An
Seung-Jeong Oh
Dae Sung Chung
Chan Eon Park
author_facet Yu Jin Kim
Tae Kyu An
Seung-Jeong Oh
Dae Sung Chung
Chan Eon Park
author_sort Yu Jin Kim
collection DOAJ
description The photovoltaic performance of a hybrid ZnO/P3HT heterojunction was improved by modifying the device surface with the MK-2 dye. This organic dye enhanced the compatibility between the polymer and the metal oxide, increased the exciton separation efficiency, and improved the molecular ordering in the charge transport network. The resulting device displayed a substantial enhancement in the photocurrent, open circuit voltage, and fill factor, leading to a 12-fold increase in the power conversion efficiency relative to the unmodified device, from 0.13% to 1.53%.
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spelling doaj.art-6e1609938bf243949aeb65a34f19fc762022-12-21T19:01:57ZengAIP Publishing LLCAPL Materials2166-532X2014-07-0127076108076108-610.1063/1.4886217002407APMSurface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performanceYu Jin Kim0Tae Kyu An1Seung-Jeong Oh2Dae Sung Chung3Chan Eon Park4POSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, South KoreaPOSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, South KoreaPOSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, South KoreaSchool of Chemical Engineering and Material Science, Chung-Ang University, Seoul 156-756, South KoreaPOSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, South KoreaThe photovoltaic performance of a hybrid ZnO/P3HT heterojunction was improved by modifying the device surface with the MK-2 dye. This organic dye enhanced the compatibility between the polymer and the metal oxide, increased the exciton separation efficiency, and improved the molecular ordering in the charge transport network. The resulting device displayed a substantial enhancement in the photocurrent, open circuit voltage, and fill factor, leading to a 12-fold increase in the power conversion efficiency relative to the unmodified device, from 0.13% to 1.53%.http://dx.doi.org/10.1063/1.4886217
spellingShingle Yu Jin Kim
Tae Kyu An
Seung-Jeong Oh
Dae Sung Chung
Chan Eon Park
Surface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performance
APL Materials
title Surface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performance
title_full Surface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performance
title_fullStr Surface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performance
title_full_unstemmed Surface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performance
title_short Surface modification with MK-2 organic dye in a ZnO/P3HT hybrid solar cell: Impact on device performance
title_sort surface modification with mk 2 organic dye in a zno p3ht hybrid solar cell impact on device performance
url http://dx.doi.org/10.1063/1.4886217
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