Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well Barrier

Utilization of natural shale formations for the creation of annular barriers in oil and gas wells is currently discussed as a mean of simplifying cumbersome plugging and abandonment procedures. Shales that are likely to form annular barriers are shales with high content of swelling clays and relativ...

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Main Authors: Kamila Gawel, Maksym Lozovyi, Mohammad Hossain Bhuiyan, Ruben Bjørge, Erling Fjær
Format: Article
Language:English
Published: MDPI AG 2021-04-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/9/2342
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author Kamila Gawel
Maksym Lozovyi
Mohammad Hossain Bhuiyan
Ruben Bjørge
Erling Fjær
author_facet Kamila Gawel
Maksym Lozovyi
Mohammad Hossain Bhuiyan
Ruben Bjørge
Erling Fjær
author_sort Kamila Gawel
collection DOAJ
description Utilization of natural shale formations for the creation of annular barriers in oil and gas wells is currently discussed as a mean of simplifying cumbersome plugging and abandonment procedures. Shales that are likely to form annular barriers are shales with high content of swelling clays and relatively low content of cementation material (e.g., quartz, carbonates). Shales with large content of quartz and low content of swelling clays will be rather brittle and not easily deformable. In this paper we ask the question whether and to what extent it is possible to modify the mechanical properties of relatively brittle shales by chemically removing some cementation material. To answer this question, we have leached out carbonates from Pierre I shale matrix using hydrochloric acid and we have compared mechanical properties of shale before and after leaching. We have also followed leaching dynamics using X-ray tomography. The results show that removal of around 4–5 wt% of cementation material results in 43% reduction in Pierre I shale shear strength compared to the non-etched shale exposed to sodium chloride solution for the same time. The etching rate was shown to be strongly affected by the volume of fluid staying in direct contact with the shale sample.
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spelling doaj.art-6e1d5f4bf74c46c9b8baadc73afa8e072023-11-21T16:34:58ZengMDPI AGEnergies1996-10732021-04-01149234210.3390/en14092342Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well BarrierKamila Gawel0Maksym Lozovyi1Mohammad Hossain Bhuiyan2Ruben Bjørge3Erling Fjær4SINTEF Industry, 7034 Trondheim, NorwayDepartment of Geoscience and Petroleum, Norwegian University of Science and Technology, 7034 Trondheim, NorwaySINTEF Industry, 7034 Trondheim, NorwaySINTEF Industry, 7034 Trondheim, NorwaySINTEF Industry, 7034 Trondheim, NorwayUtilization of natural shale formations for the creation of annular barriers in oil and gas wells is currently discussed as a mean of simplifying cumbersome plugging and abandonment procedures. Shales that are likely to form annular barriers are shales with high content of swelling clays and relatively low content of cementation material (e.g., quartz, carbonates). Shales with large content of quartz and low content of swelling clays will be rather brittle and not easily deformable. In this paper we ask the question whether and to what extent it is possible to modify the mechanical properties of relatively brittle shales by chemically removing some cementation material. To answer this question, we have leached out carbonates from Pierre I shale matrix using hydrochloric acid and we have compared mechanical properties of shale before and after leaching. We have also followed leaching dynamics using X-ray tomography. The results show that removal of around 4–5 wt% of cementation material results in 43% reduction in Pierre I shale shear strength compared to the non-etched shale exposed to sodium chloride solution for the same time. The etching rate was shown to be strongly affected by the volume of fluid staying in direct contact with the shale sample.https://www.mdpi.com/1996-1073/14/9/2342shalecaprockactivationpermanent barrieracid treatment
spellingShingle Kamila Gawel
Maksym Lozovyi
Mohammad Hossain Bhuiyan
Ruben Bjørge
Erling Fjær
Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well Barrier
Energies
shale
caprock
activation
permanent barrier
acid treatment
title Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well Barrier
title_full Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well Barrier
title_fullStr Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well Barrier
title_full_unstemmed Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well Barrier
title_short Acid Treatment as a Way to Reduce Shale Rock Mechanical Strength and to Create a Material Prone to the Formation of Permanent Well Barrier
title_sort acid treatment as a way to reduce shale rock mechanical strength and to create a material prone to the formation of permanent well barrier
topic shale
caprock
activation
permanent barrier
acid treatment
url https://www.mdpi.com/1996-1073/14/9/2342
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AT mohammadhossainbhuiyan acidtreatmentasawaytoreduceshalerockmechanicalstrengthandtocreateamaterialpronetotheformationofpermanentwellbarrier
AT rubenbjørge acidtreatmentasawaytoreduceshalerockmechanicalstrengthandtocreateamaterialpronetotheformationofpermanentwellbarrier
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