Gas Adsorption and Storage at Metal-Organic Frameworks
Dry gas is considered one of the most environmentally friendly sources of energy. As a result, developing an efficient strategy for storing this gas has become essential. In this work, MOF-199 was synthesized and characterized in order to investigate the MOF-199 in dry gas adsorption using a built-i...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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University of Baghdad
2022-01-01
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| Series: | Journal of Engineering |
| Subjects: | |
| Online Access: | https://joe.uobaghdad.edu.iq/index.php/main/article/view/1413 |
| _version_ | 1797765202062606336 |
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| author | Jamil Yousef Ahmed Rana Th. ABD Alrubaye |
| author_facet | Jamil Yousef Ahmed Rana Th. ABD Alrubaye |
| author_sort | Jamil Yousef Ahmed |
| collection | DOAJ |
| description | Dry gas is considered one of the most environmentally friendly sources of energy. As a result, developing an efficient strategy for storing this gas has become essential. In this work, MOF-199 was synthesized and characterized in order to investigate the MOF-199 in dry gas adsorption using a built-in volumetric system (methane, ethane, and propane from Basrah gas company). The MOF-199 (metal organic framework) was synthesized using the solvothermal method at 373K for 24h, and then it was characterized. The dry gas adsorption on MOF-199 was studied under various conditions (adsorbent dosage, contact time, temperature, and pressure). The isothermal adsorption of the dry gas had been studied on MOF-199 using two types of models: Freundlich and Langmuir. The results of the isothermal adsorption shown corresponded to the Freundlich model with a correlation coefficient (R²) of 0.9426. Also, the rate of adsorption kinetic of the first and second-order was studied, and the results showed that the reaction rate was second-order. |
| first_indexed | 2024-03-12T20:07:22Z |
| format | Article |
| id | doaj.art-6e20d046a85c415c8e24abc17fbe76dd |
| institution | Directory Open Access Journal |
| issn | 1726-4073 2520-3339 |
| language | English |
| last_indexed | 2024-03-12T20:07:22Z |
| publishDate | 2022-01-01 |
| publisher | University of Baghdad |
| record_format | Article |
| series | Journal of Engineering |
| spelling | doaj.art-6e20d046a85c415c8e24abc17fbe76dd2023-08-02T01:59:55ZengUniversity of BaghdadJournal of Engineering1726-40732520-33392022-01-0128110.31026/j.eng.2022.01.05Gas Adsorption and Storage at Metal-Organic FrameworksJamil Yousef Ahmed0Rana Th. ABD Alrubaye 1College of Engineering - University of BaghdadCollege of Engineering - University of BaghdadDry gas is considered one of the most environmentally friendly sources of energy. As a result, developing an efficient strategy for storing this gas has become essential. In this work, MOF-199 was synthesized and characterized in order to investigate the MOF-199 in dry gas adsorption using a built-in volumetric system (methane, ethane, and propane from Basrah gas company). The MOF-199 (metal organic framework) was synthesized using the solvothermal method at 373K for 24h, and then it was characterized. The dry gas adsorption on MOF-199 was studied under various conditions (adsorbent dosage, contact time, temperature, and pressure). The isothermal adsorption of the dry gas had been studied on MOF-199 using two types of models: Freundlich and Langmuir. The results of the isothermal adsorption shown corresponded to the Freundlich model with a correlation coefficient (R²) of 0.9426. Also, the rate of adsorption kinetic of the first and second-order was studied, and the results showed that the reaction rate was second-order.https://joe.uobaghdad.edu.iq/index.php/main/article/view/1413adsorption, mof-199, dry gas |
| spellingShingle | Jamil Yousef Ahmed Rana Th. ABD Alrubaye Gas Adsorption and Storage at Metal-Organic Frameworks Journal of Engineering adsorption, mof-199, dry gas |
| title | Gas Adsorption and Storage at Metal-Organic Frameworks |
| title_full | Gas Adsorption and Storage at Metal-Organic Frameworks |
| title_fullStr | Gas Adsorption and Storage at Metal-Organic Frameworks |
| title_full_unstemmed | Gas Adsorption and Storage at Metal-Organic Frameworks |
| title_short | Gas Adsorption and Storage at Metal-Organic Frameworks |
| title_sort | gas adsorption and storage at metal organic frameworks |
| topic | adsorption, mof-199, dry gas |
| url | https://joe.uobaghdad.edu.iq/index.php/main/article/view/1413 |
| work_keys_str_mv | AT jamilyousefahmed gasadsorptionandstorageatmetalorganicframeworks AT ranathabdalrubaye gasadsorptionandstorageatmetalorganicframeworks |