Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II)
In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N′,N′′-tridentate chelating agent, making two five-membered rings with the ZnII ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted s...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810050671 |
| _version_ | 1818776173482606592 |
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| author | Hapipah Mohd Ali Hamid Khaledi Nura Suleiman Gwaram Nurul Azimah Ikmal Hisham |
| author_facet | Hapipah Mohd Ali Hamid Khaledi Nura Suleiman Gwaram Nurul Azimah Ikmal Hisham |
| author_sort | Hapipah Mohd Ali |
| collection | DOAJ |
| description | In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N′,N′′-tridentate chelating agent, making two five-membered rings with the ZnII ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intramolecular C—H...Cl interaction occurs. In the crystal, adjacent molecules are linked together via C—H...Cl hydrogen-bonding and long range C—H...O and C—H...Cl interactions into a three-dimensional network. |
| first_indexed | 2024-12-18T11:08:43Z |
| format | Article |
| id | doaj.art-6e59f3c6a20744e49ad8bfd92cc40eaf |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T11:08:43Z |
| publishDate | 2011-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6e59f3c6a20744e49ad8bfd92cc40eaf2022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m55m5510.1107/S1600536810050671Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II)Hapipah Mohd AliHamid KhalediNura Suleiman GwaramNurul Azimah Ikmal HishamIn the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N′,N′′-tridentate chelating agent, making two five-membered rings with the ZnII ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intramolecular C—H...Cl interaction occurs. In the crystal, adjacent molecules are linked together via C—H...Cl hydrogen-bonding and long range C—H...O and C—H...Cl interactions into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536810050671 |
| spellingShingle | Hapipah Mohd Ali Hamid Khaledi Nura Suleiman Gwaram Nurul Azimah Ikmal Hisham Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II) Acta Crystallographica Section E |
| title | Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II) |
| title_full | Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II) |
| title_fullStr | Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II) |
| title_full_unstemmed | Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II) |
| title_short | Dichlorido{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N′′}zinc(II) |
| title_sort | dichlorido 2 morpholino n 1 2 pyridyl ethylidene ethanamine amp 954 3n n amp 8242 n amp 8242 amp 8242 zinc ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810050671 |
| work_keys_str_mv | AT hapipahmohdali dichlorido2morpholinon12pyridylethylideneethanamineamp9543nnamp8242namp8242amp8242zincii AT hamidkhaledi dichlorido2morpholinon12pyridylethylideneethanamineamp9543nnamp8242namp8242amp8242zincii AT nurasuleimangwaram dichlorido2morpholinon12pyridylethylideneethanamineamp9543nnamp8242namp8242amp8242zincii AT nurulazimahikmalhisham dichlorido2morpholinon12pyridylethylideneethanamineamp9543nnamp8242namp8242amp8242zincii |