Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV)
Mixedآ catechol- آ salicyladiminenate derivatives of antimony ) (III) and tin (IV) of the general formula M(cate)L"]X, [where:M= Sb, X= آ 0; آ M=Sn, آ X= آ Cl; آ cate=catechol; آ n=l, آ L=aniline, آ n=2, آ L=mآ bromo-aniline, n=3, L=p-bromo...
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| Format: | Article |
| Language: | English |
| Published: |
University of Baghdad
2017-09-01
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| Series: | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| Online Access: | https://jih.uobaghdad.edu.iq/index.php/j/article/view/1468 |
| _version_ | 1817982503293550592 |
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| author | M. J. M. J. Al-Jeboori H. A. H. A. Hasan L. K. L. K. Abdul Karim |
| author_facet | M. J. M. J. Al-Jeboori H. A. H. A. Hasan L. K. L. K. Abdul Karim |
| author_sort | M. J. M. J. Al-Jeboori |
| collection | DOAJ |
| description |
Mixedآ catechol- آ salicyladiminenate derivatives of antimony
)
(III) and tin (IV) of the general formula M(cate)L"]X, [where:M= Sb, X= آ 0; آ M=Sn, آ X= آ Cl; آ cate=catechol; آ n=l, آ L=aniline, آ n=2, آ L=mآ bromo-aniline, n=3, L=p-bromoaniline] were prepared by the reaction of equimolar amount of [(cate)MCln], [where n=l آ or 2] with Nآ arylsalicylaldimines HOC6H4CH=NC6Hs (HL1آ , HOC6H4CH= NC6H4
)
(HL1
and p-HOC6H4CH = NC6 Br (HL3)Ø¢ in methanol as a solvent.
These new derivatives were characterised by elemental analysis and spectroscopic methods [(I.R), (U.V-Vis) and ctH, 13C NMR for HL2آ ] along with conductivity and melting point measurements.آ آ These studies آ revealed آ that آ the آ geometry about آ Sb آ (ill) آ and آ Sn آ (IV) is
tetrahedral.
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| first_indexed | 2024-04-13T23:21:36Z |
| format | Article |
| id | doaj.art-6e5ea11fb3f941b49f34a65eda78c00a |
| institution | Directory Open Access Journal |
| issn | 1609-4042 2521-3407 |
| language | English |
| last_indexed | 2024-04-13T23:21:36Z |
| publishDate | 2017-09-01 |
| publisher | University of Baghdad |
| record_format | Article |
| series | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| spelling | doaj.art-6e5ea11fb3f941b49f34a65eda78c00a2022-12-22T02:25:13ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072017-09-01214Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV)M. J. M. J. Al-JebooriH. A. H. A. HasanL. K. L. K. Abdul Karim Mixedآ catechol- آ salicyladiminenate derivatives of antimony ) (III) and tin (IV) of the general formula M(cate)L"]X, [where:M= Sb, X= آ 0; آ M=Sn, آ X= آ Cl; آ cate=catechol; آ n=l, آ L=aniline, آ n=2, آ L=mآ bromo-aniline, n=3, L=p-bromoaniline] were prepared by the reaction of equimolar amount of [(cate)MCln], [where n=l آ or 2] with Nآ arylsalicylaldimines HOC6H4CH=NC6Hs (HL1آ , HOC6H4CH= NC6H4 ) (HL1 and p-HOC6H4CH = NC6 Br (HL3)آ in methanol as a solvent. These new derivatives were characterised by elemental analysis and spectroscopic methods [(I.R), (U.V-Vis) and ctH, 13C NMR for HL2آ ] along with conductivity and melting point measurements.آ آ These studies آ revealed آ that آ the آ geometry about آ Sb آ (ill) آ and آ Sn آ (IV) is tetrahedral. https://jih.uobaghdad.edu.iq/index.php/j/article/view/1468 |
| spellingShingle | M. J. M. J. Al-Jeboori H. A. H. A. Hasan L. K. L. K. Abdul Karim Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV) Ibn Al-Haitham Journal for Pure and Applied Sciences |
| title | Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV) |
| title_full | Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV) |
| title_fullStr | Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV) |
| title_full_unstemmed | Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV) |
| title_short | Synthesis and Spectroscopic Studies of Mixed Catechol-Salicylaldiminate Derivatives of Antimony (III) and Tin (IV) |
| title_sort | synthesis and spectroscopic studies of mixed catechol salicylaldiminate derivatives of antimony iii and tin iv |
| url | https://jih.uobaghdad.edu.iq/index.php/j/article/view/1468 |
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