Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FET

A stable doping technique for modifying the conduction behaviour of two-dimensional (2D) nanomaterial-based transistors is imperative for applications based on low-power complementary oxide thin-film transistors. Achieving an ambipolar feature with a controlled threshold voltage in both the p- and n...

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Main Authors: Soojin Kim, Yeeun Roh, Younguk Choi, Ah Hyun Jun, Hojun Seo, Byeong-Kwon Ju
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/12/8/3840
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author Soojin Kim
Yeeun Roh
Younguk Choi
Ah Hyun Jun
Hojun Seo
Byeong-Kwon Ju
author_facet Soojin Kim
Yeeun Roh
Younguk Choi
Ah Hyun Jun
Hojun Seo
Byeong-Kwon Ju
author_sort Soojin Kim
collection DOAJ
description A stable doping technique for modifying the conduction behaviour of two-dimensional (2D) nanomaterial-based transistors is imperative for applications based on low-power complementary oxide thin-film transistors. Achieving an ambipolar feature with a controlled threshold voltage in both the p- and n-regimes is crucial for applying MoTe<sub>2</sub>-based devices as electronic devices because their native doping states are unipolar. In this study, a simple method to tune the threshold voltage of MoTe<sub>2</sub> field-effect transistors (FETs) was investigated in order to realise an enhancement-mode MoTe<sub>2</sub> thin-film transistor by implementing a facile method to modulate the carrier polarity based on the oxidative properties of MoTe<sub>2</sub> FETs. Annealing in air induced a continuous p-doping effect in the devices without significant electrical degradation. Through a precise control of the duration and temperature of the post-annealing process, the tailoring technique induces hole doping, which results in a remarkable shift in transfer characteristics, thus leading to a charge neutrality point of the devices at zero gate bias. This study demonstrates the considerable potential of air heating as a reliable and economical post-processing method for precisely modifying the threshold voltage and further controlling the doping states of MoTe<sub>2</sub>-based FETs for use in logic inverters with 2D semiconductors.
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spelling doaj.art-6e633e2981844e2b9071fba8c33ee0d32023-12-01T00:39:53ZengMDPI AGApplied Sciences2076-34172022-04-01128384010.3390/app12083840Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FETSoojin Kim0Yeeun Roh1Younguk Choi2Ah Hyun Jun3Hojun Seo4Byeong-Kwon Ju5Department of Micro/Nano System, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, KoreaSchool of Electrical Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, KoreaSchool of Electrical Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, KoreaSchool of Electrical Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, KoreaDepartment of Electronic Engineering, Hanyang University, Seoul 04763, KoreaSchool of Electrical Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 02841, KoreaA stable doping technique for modifying the conduction behaviour of two-dimensional (2D) nanomaterial-based transistors is imperative for applications based on low-power complementary oxide thin-film transistors. Achieving an ambipolar feature with a controlled threshold voltage in both the p- and n-regimes is crucial for applying MoTe<sub>2</sub>-based devices as electronic devices because their native doping states are unipolar. In this study, a simple method to tune the threshold voltage of MoTe<sub>2</sub> field-effect transistors (FETs) was investigated in order to realise an enhancement-mode MoTe<sub>2</sub> thin-film transistor by implementing a facile method to modulate the carrier polarity based on the oxidative properties of MoTe<sub>2</sub> FETs. Annealing in air induced a continuous p-doping effect in the devices without significant electrical degradation. Through a precise control of the duration and temperature of the post-annealing process, the tailoring technique induces hole doping, which results in a remarkable shift in transfer characteristics, thus leading to a charge neutrality point of the devices at zero gate bias. This study demonstrates the considerable potential of air heating as a reliable and economical post-processing method for precisely modifying the threshold voltage and further controlling the doping states of MoTe<sub>2</sub>-based FETs for use in logic inverters with 2D semiconductors.https://www.mdpi.com/2076-3417/12/8/3840MoTe<sub>2</sub>transition metal dichalcogenidesfield-effect transistorsdopingthreshold voltagecharge neutrality
spellingShingle Soojin Kim
Yeeun Roh
Younguk Choi
Ah Hyun Jun
Hojun Seo
Byeong-Kwon Ju
Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FET
Applied Sciences
MoTe<sub>2</sub>
transition metal dichalcogenides
field-effect transistors
doping
threshold voltage
charge neutrality
title Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FET
title_full Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FET
title_fullStr Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FET
title_full_unstemmed Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FET
title_short Air Annealing Process for Threshold Voltage Tuning of MoTe<sub>2</sub> FET
title_sort air annealing process for threshold voltage tuning of mote sub 2 sub fet
topic MoTe<sub>2</sub>
transition metal dichalcogenides
field-effect transistors
doping
threshold voltage
charge neutrality
url https://www.mdpi.com/2076-3417/12/8/3840
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