Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate)
The title complex, [Cu2(C13H11F2N6O)2](ClO4)2, which was hydrothermally synthesized, contains a binuclear copper cluster (2 symmetry) with a Cu2O2 rhombus [Cu—O = 1.927 (2) Å] formed by donation of two O atoms from two chelate rings. The trident...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810008512 |
| _version_ | 1819349381731581952 |
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| author | Zhi-Rong Luo Fei-Long Hu Yue Zhuang Xian-Hong Yin Qiao-Lan Wu |
| author_facet | Zhi-Rong Luo Fei-Long Hu Yue Zhuang Xian-Hong Yin Qiao-Lan Wu |
| author_sort | Zhi-Rong Luo |
| collection | DOAJ |
| description | The title complex, [Cu2(C13H11F2N6O)2](ClO4)2, which was hydrothermally synthesized, contains a binuclear copper cluster (2 symmetry) with a Cu2O2 rhombus [Cu—O = 1.927 (2) Å] formed by donation of two O atoms from two chelate rings. The tridentate function of each ligand is completed by two N atoms coordinated to the two CuII atoms [Cu—N = 1.933 (2) Å]. The separation distance of two CuII atoms in a cluster is 2.988 (1) Å. The dihedral angle between the six-membered chelate rings is 2.13 (9)°. The perchlorate counter-anion is disordered over two sites in a 0.58 (10):0.42 (10) ratio. |
| first_indexed | 2024-12-24T18:59:37Z |
| format | Article |
| id | doaj.art-6e65eac9d4ed4b84bb86980e156585ad |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T18:59:37Z |
| publishDate | 2010-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6e65eac9d4ed4b84bb86980e156585ad2022-12-21T16:43:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m391m39110.1107/S1600536810008512Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate)Zhi-Rong LuoFei-Long HuYue ZhuangXian-Hong YinQiao-Lan WuThe title complex, [Cu2(C13H11F2N6O)2](ClO4)2, which was hydrothermally synthesized, contains a binuclear copper cluster (2 symmetry) with a Cu2O2 rhombus [Cu—O = 1.927 (2) Å] formed by donation of two O atoms from two chelate rings. The tridentate function of each ligand is completed by two N atoms coordinated to the two CuII atoms [Cu—N = 1.933 (2) Å]. The separation distance of two CuII atoms in a cluster is 2.988 (1) Å. The dihedral angle between the six-membered chelate rings is 2.13 (9)°. The perchlorate counter-anion is disordered over two sites in a 0.58 (10):0.42 (10) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536810008512 |
| spellingShingle | Zhi-Rong Luo Fei-Long Hu Yue Zhuang Xian-Hong Yin Qiao-Lan Wu Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate) Acta Crystallographica Section E |
| title | Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate) |
| title_full | Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate) |
| title_fullStr | Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate) |
| title_full_unstemmed | Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate) |
| title_short | Bis[μ-2-(2,4-difluorophenyl)-1,3-bis(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis(perchlorate) |
| title_sort | bis amp 956 2 2 4 difluorophenyl 1 3 bis 1h 1 2 4 triazol 1 yl propan 2 olato dicopper ii bis perchlorate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810008512 |
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