Raman and Photoluminescence Mapping of Gem Materials

Raman and photoluminescence (PL) mapping is a non-destructive method which allows gemologists and scientists to evaluate the spatial distributions of defects within a gem; it can also provide a method to quickly distinguish different species within a composite gem. This article provides a summary of...

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Main Authors: Sally Eaton-Magaña, Christopher M. Breeding, Aaron C. Palke, Artitaya Homkrajae, Ziyin Sun, Garrett McElhenny
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/11/2/177
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author Sally Eaton-Magaña
Christopher M. Breeding
Aaron C. Palke
Artitaya Homkrajae
Ziyin Sun
Garrett McElhenny
author_facet Sally Eaton-Magaña
Christopher M. Breeding
Aaron C. Palke
Artitaya Homkrajae
Ziyin Sun
Garrett McElhenny
author_sort Sally Eaton-Magaña
collection DOAJ
description Raman and photoluminescence (PL) mapping is a non-destructive method which allows gemologists and scientists to evaluate the spatial distributions of defects within a gem; it can also provide a method to quickly distinguish different species within a composite gem. This article provides a summary of this relatively new technology and its instrumentation. Additionally, we provide a compilation of new data for various applications on several gemstones. Spatial differences within diamonds can be explored using PL mapping, such as radiation stains observed on the rough surface of natural green diamonds. Raman mapping has proven useful in distinguishing between omphacite and jadeite within a composite of these two minerals, identifying various tourmaline species within a heterogeneous mixture, and determining the calcium carbonate polymorphs in pearls. Additionally, it has potential to be useful for country-of-origin determination in blue sapphires and micro-inclusion analysis. As new avenues of research are explored, more applications for gem materials will inevitably be discovered.
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spelling doaj.art-6e68642bca264c70a658957385f6629c2023-12-03T12:53:08ZengMDPI AGMinerals2075-163X2021-02-0111217710.3390/min11020177Raman and Photoluminescence Mapping of Gem MaterialsSally Eaton-Magaña0Christopher M. Breeding1Aaron C. Palke2Artitaya Homkrajae3Ziyin Sun4Garrett McElhenny5Gemological Institute of America, Carlsbad, CA 92008, USAGemological Institute of America, Carlsbad, CA 92008, USAGemological Institute of America, Carlsbad, CA 92008, USAGemological Institute of America, Carlsbad, CA 92008, USAGemological Institute of America, Carlsbad, CA 92008, USAGemological Institute of America, Carlsbad, CA 92008, USARaman and photoluminescence (PL) mapping is a non-destructive method which allows gemologists and scientists to evaluate the spatial distributions of defects within a gem; it can also provide a method to quickly distinguish different species within a composite gem. This article provides a summary of this relatively new technology and its instrumentation. Additionally, we provide a compilation of new data for various applications on several gemstones. Spatial differences within diamonds can be explored using PL mapping, such as radiation stains observed on the rough surface of natural green diamonds. Raman mapping has proven useful in distinguishing between omphacite and jadeite within a composite of these two minerals, identifying various tourmaline species within a heterogeneous mixture, and determining the calcium carbonate polymorphs in pearls. Additionally, it has potential to be useful for country-of-origin determination in blue sapphires and micro-inclusion analysis. As new avenues of research are explored, more applications for gem materials will inevitably be discovered.https://www.mdpi.com/2075-163X/11/2/177Raman mappingphotoluminescence mappingspectroscopydiamondcorundumtourmaline
spellingShingle Sally Eaton-Magaña
Christopher M. Breeding
Aaron C. Palke
Artitaya Homkrajae
Ziyin Sun
Garrett McElhenny
Raman and Photoluminescence Mapping of Gem Materials
Minerals
Raman mapping
photoluminescence mapping
spectroscopy
diamond
corundum
tourmaline
title Raman and Photoluminescence Mapping of Gem Materials
title_full Raman and Photoluminescence Mapping of Gem Materials
title_fullStr Raman and Photoluminescence Mapping of Gem Materials
title_full_unstemmed Raman and Photoluminescence Mapping of Gem Materials
title_short Raman and Photoluminescence Mapping of Gem Materials
title_sort raman and photoluminescence mapping of gem materials
topic Raman mapping
photoluminescence mapping
spectroscopy
diamond
corundum
tourmaline
url https://www.mdpi.com/2075-163X/11/2/177
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AT artitayahomkrajae ramanandphotoluminescencemappingofgemmaterials
AT ziyinsun ramanandphotoluminescencemappingofgemmaterials
AT garrettmcelhenny ramanandphotoluminescencemappingofgemmaterials