Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubes

Abstract Alternatives to conventional Portland cement with a more sustainable appeal are increasingly recurrent. Among these are the Limestone Calcined Clay (LC3) systems, characterized by high replacement percentages of Portland clinker by calcined clay and limestone, materials widely available wo...

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Main Authors: Laura Silvestro, Artur Spat Ruviaro, Francisco Roger Carneiro Ribeiro, Philippe Jean Paul Gleize, Ana Paula Kirchheim
Format: Article
Language:English
Published: Instituto Brasileiro do Concreto (IBRACON) 2023-06-01
Series:Revista IBRACON de Estruturas e Materiais
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952024000100207&tlng=en
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author Laura Silvestro
Artur Spat Ruviaro
Francisco Roger Carneiro Ribeiro
Philippe Jean Paul Gleize
Ana Paula Kirchheim
author_facet Laura Silvestro
Artur Spat Ruviaro
Francisco Roger Carneiro Ribeiro
Philippe Jean Paul Gleize
Ana Paula Kirchheim
author_sort Laura Silvestro
collection DOAJ
description Abstract Alternatives to conventional Portland cement with a more sustainable appeal are increasingly recurrent. Among these are the Limestone Calcined Clay (LC3) systems, characterized by high replacement percentages of Portland clinker by calcined clay and limestone, materials widely available worldwide. A complete understanding of the rheological behavior of LC3 systems is necessary for the practical application of this type of cement to be consolidated. Furthermore, although not yet investigated, the incorporation of nanomaterials stands out as a promising alternative for accelerating reactions and enhancing the mechanical performance of these systems at early ages. This study investigated the incorporation of carbon nanotubes (CNT) contents from 0.05 to 0.125% in an LC3 system through rotational rheometry, isothermal calorimetry, compressive strength at 7 and 28 days, and X-ray diffraction. Although the CNT incorporation increased the dynamic yield stress and equivalent viscosity of the LC3 pastes, the content of 0.1 wt.% slightly increased and anticipated the occurrence of the main peak of the aluminates. Increases of up to 13.5% in compressive strength at 7 and 28 days of hydration were observed for a CNT content of 0.1 wt.%.
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spelling doaj.art-6e86f8bae8dc4cecb5d0f9d5e202cd872023-06-30T10:53:26ZengInstituto Brasileiro do Concreto (IBRACON)Revista IBRACON de Estruturas e Materiais1983-41952023-06-0117110.1590/s1983-41952024000100006Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubesLaura Silvestrohttps://orcid.org/0000-0002-6437-3047Artur Spat Ruviarohttps://orcid.org/0000-0003-0903-7646Francisco Roger Carneiro Ribeirohttps://orcid.org/0000-0001-8790-3023Philippe Jean Paul Gleizehttps://orcid.org/0000-0003-4029-9345Ana Paula Kirchheimhttps://orcid.org/0000-0002-8241-0331 Abstract Alternatives to conventional Portland cement with a more sustainable appeal are increasingly recurrent. Among these are the Limestone Calcined Clay (LC3) systems, characterized by high replacement percentages of Portland clinker by calcined clay and limestone, materials widely available worldwide. A complete understanding of the rheological behavior of LC3 systems is necessary for the practical application of this type of cement to be consolidated. Furthermore, although not yet investigated, the incorporation of nanomaterials stands out as a promising alternative for accelerating reactions and enhancing the mechanical performance of these systems at early ages. This study investigated the incorporation of carbon nanotubes (CNT) contents from 0.05 to 0.125% in an LC3 system through rotational rheometry, isothermal calorimetry, compressive strength at 7 and 28 days, and X-ray diffraction. Although the CNT incorporation increased the dynamic yield stress and equivalent viscosity of the LC3 pastes, the content of 0.1 wt.% slightly increased and anticipated the occurrence of the main peak of the aluminates. Increases of up to 13.5% in compressive strength at 7 and 28 days of hydration were observed for a CNT content of 0.1 wt.%.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952024000100207&tlng=enLC3carbon nanotubescompositesrheologyhydration
spellingShingle Laura Silvestro
Artur Spat Ruviaro
Francisco Roger Carneiro Ribeiro
Philippe Jean Paul Gleize
Ana Paula Kirchheim
Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubes
Revista IBRACON de Estruturas e Materiais
LC3
carbon nanotubes
composites
rheology
hydration
title Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubes
title_full Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubes
title_fullStr Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubes
title_full_unstemmed Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubes
title_short Rheological behavior, hydration, and mechanical properties of LC3 systems with the incorporation of functionalized multi-walled carbon nanotubes
title_sort rheological behavior hydration and mechanical properties of lc3 systems with the incorporation of functionalized multi walled carbon nanotubes
topic LC3
carbon nanotubes
composites
rheology
hydration
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1983-41952024000100207&tlng=en
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AT franciscorogercarneiroribeiro rheologicalbehaviorhydrationandmechanicalpropertiesoflc3systemswiththeincorporationoffunctionalizedmultiwalledcarbonnanotubes
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