Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate
In the cobaltocenium group of the title compound, [AuCo(C5H5)(C17H14P)Cl]PF6, the substituted cyclopentadienyl (Cps) and the unsubstituted cyclopentadienyl (Cp) ring planes are almost parallel, making a dihedral angle of 3.1 (3)°. The C atoms in Cp and Cps are in an eclips...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811018769 |
| _version_ | 1818322907586101248 |
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| author | Xiang-Hua Wu |
| author_facet | Xiang-Hua Wu |
| author_sort | Xiang-Hua Wu |
| collection | DOAJ |
| description | In the cobaltocenium group of the title compound, [AuCo(C5H5)(C17H14P)Cl]PF6, the substituted cyclopentadienyl (Cps) and the unsubstituted cyclopentadienyl (Cp) ring planes are almost parallel, making a dihedral angle of 3.1 (3)°. The C atoms in Cp and Cps are in an eclipsed conformation. The AuI atom is coordinated by a P atom from the diphenylphosphanyl group and a Cl atom in an almost linear arrangement [P—Au—Cl = 178.15–(7)°]. Two hexafluoridophosphate anions are each located on a twofold rotation axis. In the crystal, the complex cations and hexafluoridophosphate anions are linked via intermolecular C—H...F hydrogen bonds. |
| first_indexed | 2024-12-13T11:04:15Z |
| format | Article |
| id | doaj.art-6e880757d5514f56adffe5e2cef5265c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T11:04:15Z |
| publishDate | 2011-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6e880757d5514f56adffe5e2cef5265c2022-12-21T23:49:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m798m79810.1107/S1600536811018769Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphateXiang-Hua WuIn the cobaltocenium group of the title compound, [AuCo(C5H5)(C17H14P)Cl]PF6, the substituted cyclopentadienyl (Cps) and the unsubstituted cyclopentadienyl (Cp) ring planes are almost parallel, making a dihedral angle of 3.1 (3)°. The C atoms in Cp and Cps are in an eclipsed conformation. The AuI atom is coordinated by a P atom from the diphenylphosphanyl group and a Cl atom in an almost linear arrangement [P—Au—Cl = 178.15–(7)°]. Two hexafluoridophosphate anions are each located on a twofold rotation axis. In the crystal, the complex cations and hexafluoridophosphate anions are linked via intermolecular C—H...F hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811018769 |
| spellingShingle | Xiang-Hua Wu Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate Acta Crystallographica Section E |
| title | Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate |
| title_full | Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate |
| title_fullStr | Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate |
| title_full_unstemmed | Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate |
| title_short | Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate |
| title_sort | chlorido 1 diphenylphosphanyl cobaltocenium gold i hexafluoridophosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811018769 |
| work_keys_str_mv | AT xianghuawu chlorido1diphenylphosphanylcobaltoceniumgoldihexafluoridophosphate |