Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts

The preparation methods of hydrophobic materials such as zeolites, modified silicas and polymers has been reviewed. Particular attention has been paid to the characterization methods classified according to the surface and bulk composition, on one hand, and to the measure of interactions with water...

Full description

Bibliographic Details
Main Authors: Denise Cavuoto, Federica Zaccheria, Nicoletta Ravasio
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/10/11/1337
_version_ 1797547696373891072
author Denise Cavuoto
Federica Zaccheria
Nicoletta Ravasio
author_facet Denise Cavuoto
Federica Zaccheria
Nicoletta Ravasio
author_sort Denise Cavuoto
collection DOAJ
description The preparation methods of hydrophobic materials such as zeolites, modified silicas and polymers has been reviewed. Particular attention has been paid to the characterization methods classified according to the surface and bulk composition, on one hand, and to the measure of interactions with water or organic solvents, on the other. Some selected applications are analyzed in order to understand the relevance of the reactants/products adsorption to address activity and selectivity of the reaction. Thus, absorption of a non-polar reactant or desorption of a hydrophilic product are much easier on a hydrophobic surface and can effectively boost the catalytic activity.
first_indexed 2024-03-10T14:47:48Z
format Article
id doaj.art-6eb5691d111b4829bddcbb5eca5d9b15
institution Directory Open Access Journal
issn 2073-4344
language English
last_indexed 2024-03-10T14:47:48Z
publishDate 2020-11-01
publisher MDPI AG
record_format Article
series Catalysts
spelling doaj.art-6eb5691d111b4829bddcbb5eca5d9b152023-11-20T21:14:47ZengMDPI AGCatalysts2073-43442020-11-011011133710.3390/catal10111337Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid CatalystsDenise Cavuoto0Federica Zaccheria1Nicoletta Ravasio2Department of Chemistry, University of Milano, Via Golgi 19, I-20133 Milano, ItalyNational Research Council, Institute of Chemical Sciences and Technologies “G. Natta”, Via C. Golgi 19, I-20133 Milano, ItalyNational Research Council, Institute of Chemical Sciences and Technologies “G. Natta”, Via C. Golgi 19, I-20133 Milano, ItalyThe preparation methods of hydrophobic materials such as zeolites, modified silicas and polymers has been reviewed. Particular attention has been paid to the characterization methods classified according to the surface and bulk composition, on one hand, and to the measure of interactions with water or organic solvents, on the other. Some selected applications are analyzed in order to understand the relevance of the reactants/products adsorption to address activity and selectivity of the reaction. Thus, absorption of a non-polar reactant or desorption of a hydrophilic product are much easier on a hydrophobic surface and can effectively boost the catalytic activity.https://www.mdpi.com/2073-4344/10/11/1337hydrophobicityheterogeneous catalysissurface wettabilityproduct desorption
spellingShingle Denise Cavuoto
Federica Zaccheria
Nicoletta Ravasio
Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts
Catalysts
hydrophobicity
heterogeneous catalysis
surface wettability
product desorption
title Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts
title_full Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts
title_fullStr Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts
title_full_unstemmed Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts
title_short Some Critical Insights into the Synthesis and Applications of Hydrophobic Solid Catalysts
title_sort some critical insights into the synthesis and applications of hydrophobic solid catalysts
topic hydrophobicity
heterogeneous catalysis
surface wettability
product desorption
url https://www.mdpi.com/2073-4344/10/11/1337
work_keys_str_mv AT denisecavuoto somecriticalinsightsintothesynthesisandapplicationsofhydrophobicsolidcatalysts
AT federicazaccheria somecriticalinsightsintothesynthesisandapplicationsofhydrophobicsolidcatalysts
AT nicolettaravasio somecriticalinsightsintothesynthesisandapplicationsofhydrophobicsolidcatalysts