An Approach to Carbon Dioxide Particle Distribution in Accidental Releases

The main problem in calculating the consequences of a carbon dioxide dispersion following an accidental release is the formation of solid CO2 during the expansion to ambient pressure. The dispersion models more frequently used in the framework of quantitative risk analysis, cannot describe the carbo...

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Main Authors: C. Hulsbosch-Dam, M. Spruijt, A. Necci, V. Cozzani
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2012-05-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/7476
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author C. Hulsbosch-Dam
M. Spruijt
A. Necci
V. Cozzani
author_facet C. Hulsbosch-Dam
M. Spruijt
A. Necci
V. Cozzani
author_sort C. Hulsbosch-Dam
collection DOAJ
description The main problem in calculating the consequences of a carbon dioxide dispersion following an accidental release is the formation of solid CO2 during the expansion to ambient pressure. The dispersion models more frequently used in the framework of quantitative risk analysis, cannot describe the carbon dioxide behaviour, in particular with respect to the calculation of the rainout fraction. Moreover, only scarce data is available for two phase CO2 releases. In the present study, a specific approach was developed to calculate the particle size distribution following the release of pressurized liquid (or supercritical) CO2. The approach combines several sub-models accounting for the different mechanisms of jet break-up and specifically addresses the possible formation of solid particles. The model was validated using experimental data available for CO2 and for the release of other pressurised, superheated liquids. The model developed can find further applications in rain-out calculations for two-phase releases of conventional substances.
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spelling doaj.art-6ebb2c9491814ec099958248428b55c12022-12-21T21:58:10ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162012-05-012610.3303/CET1226091An Approach to Carbon Dioxide Particle Distribution in Accidental ReleasesC. Hulsbosch-DamM. SpruijtA. NecciV. CozzaniThe main problem in calculating the consequences of a carbon dioxide dispersion following an accidental release is the formation of solid CO2 during the expansion to ambient pressure. The dispersion models more frequently used in the framework of quantitative risk analysis, cannot describe the carbon dioxide behaviour, in particular with respect to the calculation of the rainout fraction. Moreover, only scarce data is available for two phase CO2 releases. In the present study, a specific approach was developed to calculate the particle size distribution following the release of pressurized liquid (or supercritical) CO2. The approach combines several sub-models accounting for the different mechanisms of jet break-up and specifically addresses the possible formation of solid particles. The model was validated using experimental data available for CO2 and for the release of other pressurised, superheated liquids. The model developed can find further applications in rain-out calculations for two-phase releases of conventional substances.https://www.cetjournal.it/index.php/cet/article/view/7476
spellingShingle C. Hulsbosch-Dam
M. Spruijt
A. Necci
V. Cozzani
An Approach to Carbon Dioxide Particle Distribution in Accidental Releases
Chemical Engineering Transactions
title An Approach to Carbon Dioxide Particle Distribution in Accidental Releases
title_full An Approach to Carbon Dioxide Particle Distribution in Accidental Releases
title_fullStr An Approach to Carbon Dioxide Particle Distribution in Accidental Releases
title_full_unstemmed An Approach to Carbon Dioxide Particle Distribution in Accidental Releases
title_short An Approach to Carbon Dioxide Particle Distribution in Accidental Releases
title_sort approach to carbon dioxide particle distribution in accidental releases
url https://www.cetjournal.it/index.php/cet/article/view/7476
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