Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)]
The asymmetric unit of the organic–inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conf...
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| Language: | English |
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International Union of Crystallography
2016-05-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016005284 |
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| author | S. Vetrivel E. Vinoth R. U. Mullai R. Aruljothi M. NizamMohideen |
| author_facet | S. Vetrivel E. Vinoth R. U. Mullai R. Aruljothi M. NizamMohideen |
| author_sort | S. Vetrivel |
| collection | DOAJ |
| description | The asymmetric unit of the organic–inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO4 tetrahedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H...O hydrogen bonds between the cations and anions and additional C—H...O interactions lead to the formation of a three-dimensional network structure. |
| first_indexed | 2024-12-24T04:23:54Z |
| format | Article |
| id | doaj.art-6ebfa9d4a76c475c8e1dc5898aa53244 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-24T04:23:54Z |
| publishDate | 2016-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-6ebfa9d4a76c475c8e1dc5898aa532442022-12-21T17:15:41ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-05-0172561661910.1107/S2056989016005284wm5281Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)]S. Vetrivel0E. Vinoth1R. U. Mullai2R. Aruljothi3M. NizamMohideen4PG & Research Department of Physics, Government Arts College, Tiruvannamalai 606 603, Tamil Nadu, IndiaPG & Research Department of Physics, Government Arts College, Tiruvannamalai 606 603, Tamil Nadu, IndiaPG & Research Department of Physics, Government Arts College, Tiruvannamalai 606 603, Tamil Nadu, IndiaPG & Research Department of Physics, Government Arts College, Tiruvannamalai 606 603, Tamil Nadu, IndiaDepartment of Physics, The New College (Autonomous), Chennai 600 014, Tamil Nadu, IndiaThe asymmetric unit of the organic–inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO4 tetrahedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H...O hydrogen bonds between the cations and anions and additional C—H...O interactions lead to the formation of a three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S2056989016005284crystal structuredichromate anionpiperazinediium cationmolecular salthydrogen bonding. |
| spellingShingle | S. Vetrivel E. Vinoth R. U. Mullai R. Aruljothi M. NizamMohideen Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] Acta Crystallographica Section E: Crystallographic Communications crystal structure dichromate anion piperazinediium cation molecular salt hydrogen bonding. |
| title | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
| title_full | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
| title_fullStr | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
| title_full_unstemmed | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
| title_short | Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)] |
| title_sort | crystal structure of 1 4 bis 3 ammoniopropyl piperazine 1 4 diium bis dichromate vi |
| topic | crystal structure dichromate anion piperazinediium cation molecular salt hydrogen bonding. |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016005284 |
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