Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solution

Deformed copper samples were burned at different temperatures. This procedure formed different dislocation density in the samples. Then such prepared samples were used as the anodes in acidic C11SO4 solution. The voltage for electrolyse was 10 mV. The experiment has shown that the increase of the di...

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Main Authors: Alexey D Vasil'ev, Sergey I Kosulin, Sergey N Balakirov
Format: Article
Language:English
Published: Samara State Technical University 2010-06-01
Series:Vestnik Samarskogo Gosudarstvennogo Tehničeskogo Universiteta. Seriâ: Fiziko-Matematičeskie Nauki
Subjects:
Online Access:https://journals.eco-vector.com/1991-8615/article/viewFile/21101/17359
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author Alexey D Vasil'ev
Sergey I Kosulin
Sergey N Balakirov
author_facet Alexey D Vasil'ev
Sergey I Kosulin
Sergey N Balakirov
author_sort Alexey D Vasil'ev
collection DOAJ
description Deformed copper samples were burned at different temperatures. This procedure formed different dislocation density in the samples. Then such prepared samples were used as the anodes in acidic C11SO4 solution. The voltage for electrolyse was 10 mV. The experiment has shown that the increase of the dislocation density in the anode leads to the increase of the density of anode current. It was discovered that the density of anode current could become 2,5 times bigger. This can be explained by the fact that dislocations decrease the potential barrier during the transfer of copper ions from the grid into the electrolyte.
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spelling doaj.art-6f0600d046bc428886e23352ff601d732022-12-22T02:40:38ZengSamara State Technical UniversityVestnik Samarskogo Gosudarstvennogo Tehničeskogo Universiteta. Seriâ: Fiziko-Matematičeskie Nauki1991-86152310-70812010-06-0114230230418518Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solutionAlexey D Vasil'ev0Sergey I Kosulin1Sergey N Balakirov2Samara State Technical UniversitySamara State Technical UniversitySamara State Technical UniversityDeformed copper samples were burned at different temperatures. This procedure formed different dislocation density in the samples. Then such prepared samples were used as the anodes in acidic C11SO4 solution. The voltage for electrolyse was 10 mV. The experiment has shown that the increase of the dislocation density in the anode leads to the increase of the density of anode current. It was discovered that the density of anode current could become 2,5 times bigger. This can be explained by the fact that dislocations decrease the potential barrier during the transfer of copper ions from the grid into the electrolyte.https://journals.eco-vector.com/1991-8615/article/viewFile/21101/17359kinetics of anode processdislocation density
spellingShingle Alexey D Vasil'ev
Sergey I Kosulin
Sergey N Balakirov
Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solution
Vestnik Samarskogo Gosudarstvennogo Tehničeskogo Universiteta. Seriâ: Fiziko-Matematičeskie Nauki
kinetics of anode process
dislocation density
title Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solution
title_full Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solution
title_fullStr Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solution
title_full_unstemmed Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solution
title_short Influence of dislocation density of copper electrode on the kinetics of anode process in acidic CuSO4 solution
title_sort influence of dislocation density of copper electrode on the kinetics of anode process in acidic cuso4 solution
topic kinetics of anode process
dislocation density
url https://journals.eco-vector.com/1991-8615/article/viewFile/21101/17359
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