Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization
Visible-light photoredox catalysis is a powerful and attractive strategy for organic molecule activation and new reaction design owing to its environmental-friendly characteristics and unique catalytic mechanisms, and has found wide applications in organic synthesis. This catalytic strategy enables...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2020-06-01
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| Series: | Green Synthesis and Catalysis |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S266655492030003X |
| _version_ | 1818606388008452096 |
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| author | Pengzi Wang Quanqing Zhao Wenjing Xiao Jiarong Chen |
| author_facet | Pengzi Wang Quanqing Zhao Wenjing Xiao Jiarong Chen |
| author_sort | Pengzi Wang |
| collection | DOAJ |
| description | Visible-light photoredox catalysis is a powerful and attractive strategy for organic molecule activation and new reaction design owing to its environmental-friendly characteristics and unique catalytic mechanisms, and has found wide applications in organic synthesis. This catalytic strategy enables controllable generation of diverse nitrogen-centered radicals (NCRs) under mild conditions, providing access to construction of diverse nitrogen-containing compounds. In this review, we critically illustrate the recent advances in the field of visible-light photoredox-catalyzed cyclization of nitrogen-centered radicals, based on the different radical precursors and activation modes. Wherever possible, particular emphasis is also put on working models and synthetic applications. |
| first_indexed | 2024-12-16T14:10:03Z |
| format | Article |
| id | doaj.art-6f06c9acc1fa43aeac4f179a3127a3ff |
| institution | Directory Open Access Journal |
| issn | 2666-5549 |
| language | English |
| last_indexed | 2024-12-16T14:10:03Z |
| publishDate | 2020-06-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Synthesis and Catalysis |
| spelling | doaj.art-6f06c9acc1fa43aeac4f179a3127a3ff2022-12-21T22:28:48ZengKeAi Communications Co. Ltd.Green Synthesis and Catalysis2666-55492020-06-01114251Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclizationPengzi Wang0Quanqing Zhao1Wenjing Xiao2Jiarong Chen3CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, ChinaCCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, ChinaCCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, ChinaCCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China; Corresponding author.Visible-light photoredox catalysis is a powerful and attractive strategy for organic molecule activation and new reaction design owing to its environmental-friendly characteristics and unique catalytic mechanisms, and has found wide applications in organic synthesis. This catalytic strategy enables controllable generation of diverse nitrogen-centered radicals (NCRs) under mild conditions, providing access to construction of diverse nitrogen-containing compounds. In this review, we critically illustrate the recent advances in the field of visible-light photoredox-catalyzed cyclization of nitrogen-centered radicals, based on the different radical precursors and activation modes. Wherever possible, particular emphasis is also put on working models and synthetic applications.http://www.sciencedirect.com/science/article/pii/S266655492030003XPhotoredox catalysisNitrogen radicalsRadical cyclization reactionsNitrogen-containing compoundsNitrogen heterocycles |
| spellingShingle | Pengzi Wang Quanqing Zhao Wenjing Xiao Jiarong Chen Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization Green Synthesis and Catalysis Photoredox catalysis Nitrogen radicals Radical cyclization reactions Nitrogen-containing compounds Nitrogen heterocycles |
| title | Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization |
| title_full | Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization |
| title_fullStr | Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization |
| title_full_unstemmed | Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization |
| title_short | Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization |
| title_sort | recent advances in visible light photoredox catalyzed nitrogen radical cyclization |
| topic | Photoredox catalysis Nitrogen radicals Radical cyclization reactions Nitrogen-containing compounds Nitrogen heterocycles |
| url | http://www.sciencedirect.com/science/article/pii/S266655492030003X |
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