Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine Tailings

The aim of this study was to evaluate the surface modification efficiency of raw zeolite by hexadecyl trimethylammonium cationic surfactant for cyanide sorption. Properties such as mineralogy, morphology and elemental composition of sorbents were determined. Batch and column tests were performed to...

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Main Authors: Mehdi Soleymani Gharegol, Kazem Badv, Behzad Nemati Akhgar
Format: Article
Language:fas
Published: Iranian Rainwater Catchment Systems Association 2023-09-01
Series:محیط زیست و مهندسی آب
Subjects:
Online Access:http://www.jewe.ir/article_153378_1b64824c45f9eec9aa55b3e744d9b81b.pdf
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author Mehdi Soleymani Gharegol
Kazem Badv
Behzad Nemati Akhgar
author_facet Mehdi Soleymani Gharegol
Kazem Badv
Behzad Nemati Akhgar
author_sort Mehdi Soleymani Gharegol
collection DOAJ
description The aim of this study was to evaluate the surface modification efficiency of raw zeolite by hexadecyl trimethylammonium cationic surfactant for cyanide sorption. Properties such as mineralogy, morphology and elemental composition of sorbents were determined. Batch and column tests were performed to evaluate the sorption efficiency of raw and modified zeolite from solution and released from the cyanide polluted pulp. The presence of clinoptilolite mineral and surfactant surface coating due to modification using surfactant was confirmed by X-ray diffraction analysis and electron microscopy images. The results of isotherm experiment showed that modification of zeolite with surfactant increased the adsorption capacity of cyanide by zeolite 7 times compared to the raw sample and the maximum adsorption capacity of cyanide by modified zeolite was 3.97 mg/g. The ability of surfactant-modified zeolite to sorb more cyanide than raw zeolite was confirmed by the results of the column test on the cyanide released from the pulp. It was observed that with increasing time, the concentration of cyanide in the outlet solution increases, but this increase in the cyanide concentration in the outlet solution of the column containing the modified zeolite is less than the raw zeolite.
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spelling doaj.art-6f22378691ab4e9a86a5521a15e0f5a32024-05-14T11:30:22ZfasIranian Rainwater Catchment Systems Associationمحیط زیست و مهندسی آب2476-36832023-09-019329630710.22034/ewe.2022.339680.1770153378Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine TailingsMehdi Soleymani Gharegol0Kazem Badv1Behzad Nemati Akhgar2PhD Alumni, , Department of Civil Engineering, Faculty of Engineering, Urmia University, Urmia, IranProfessor, Department of Civil Engineering, Faculty of Engineering, Urmia University, Urmia, IranAssist. Professor, Department of Mining Engineering, Faculty of Engineering, Urmia University, Urmia, IranThe aim of this study was to evaluate the surface modification efficiency of raw zeolite by hexadecyl trimethylammonium cationic surfactant for cyanide sorption. Properties such as mineralogy, morphology and elemental composition of sorbents were determined. Batch and column tests were performed to evaluate the sorption efficiency of raw and modified zeolite from solution and released from the cyanide polluted pulp. The presence of clinoptilolite mineral and surfactant surface coating due to modification using surfactant was confirmed by X-ray diffraction analysis and electron microscopy images. The results of isotherm experiment showed that modification of zeolite with surfactant increased the adsorption capacity of cyanide by zeolite 7 times compared to the raw sample and the maximum adsorption capacity of cyanide by modified zeolite was 3.97 mg/g. The ability of surfactant-modified zeolite to sorb more cyanide than raw zeolite was confirmed by the results of the column test on the cyanide released from the pulp. It was observed that with increasing time, the concentration of cyanide in the outlet solution increases, but this increase in the cyanide concentration in the outlet solution of the column containing the modified zeolite is less than the raw zeolite.http://www.jewe.ir/article_153378_1b64824c45f9eec9aa55b3e744d9b81b.pdfadsorption isothermclinoptilolitecolumn testpulp
spellingShingle Mehdi Soleymani Gharegol
Kazem Badv
Behzad Nemati Akhgar
Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine Tailings
محیط زیست و مهندسی آب
adsorption isotherm
clinoptilolite
column test
pulp
title Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine Tailings
title_full Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine Tailings
title_fullStr Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine Tailings
title_full_unstemmed Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine Tailings
title_short Efficiency Assessment of Cyanide Adsorption Using Zeolite Modified with Cationic Surfactant from Gold Mine Tailings
title_sort efficiency assessment of cyanide adsorption using zeolite modified with cationic surfactant from gold mine tailings
topic adsorption isotherm
clinoptilolite
column test
pulp
url http://www.jewe.ir/article_153378_1b64824c45f9eec9aa55b3e744d9b81b.pdf
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AT kazembadv efficiencyassessmentofcyanideadsorptionusingzeolitemodifiedwithcationicsurfactantfromgoldminetailings
AT behzadnematiakhgar efficiencyassessmentofcyanideadsorptionusingzeolitemodifiedwithcationicsurfactantfromgoldminetailings