cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrate
In the title compound {systematic name: cis-bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato-κ2N,N′]bis(butylamine-κN)copper(II) pentahydrate}, [Cu(C10H9N4O2S)2(C4H11N)2]·5H2O or [Cu(sdz)2(ba)2]·5H2O [ba is butylamine and sdz = sulfadiazine(1−...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808026457 |
| _version_ | 1818971282858835968 |
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| author | Orhan Büyükgüngör Zerrin Heren Gökhan Kaştaş Hümeyra Paşaoğlu |
| author_facet | Orhan Büyükgüngör Zerrin Heren Gökhan Kaştaş Hümeyra Paşaoğlu |
| author_sort | Orhan Büyükgüngör |
| collection | DOAJ |
| description | In the title compound {systematic name: cis-bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato-κ2N,N′]bis(butylamine-κN)copper(II) pentahydrate}, [Cu(C10H9N4O2S)2(C4H11N)2]·5H2O or [Cu(sdz)2(ba)2]·5H2O [ba is butylamine and sdz = sulfadiazine(1−)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butylamine ligands. The copper(II) ion and one of the water molecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetrahedral. The crystal structure involves intermolecular N—H...N and N—H...O hydrogen bonds. N—H...N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane. |
| first_indexed | 2024-12-20T14:49:54Z |
| format | Article |
| id | doaj.art-6f31f3edd173496e92808b052aa6a3f3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T14:49:54Z |
| publishDate | 2008-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-6f31f3edd173496e92808b052aa6a3f32022-12-21T19:36:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1192m119210.1107/S1600536808026457cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrateOrhan BüyükgüngörZerrin HerenGökhan KaştaşHümeyra PaşaoğluIn the title compound {systematic name: cis-bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato-κ2N,N′]bis(butylamine-κN)copper(II) pentahydrate}, [Cu(C10H9N4O2S)2(C4H11N)2]·5H2O or [Cu(sdz)2(ba)2]·5H2O [ba is butylamine and sdz = sulfadiazine(1−)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butylamine ligands. The copper(II) ion and one of the water molecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetrahedral. The crystal structure involves intermolecular N—H...N and N—H...O hydrogen bonds. N—H...N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane.http://scripts.iucr.org/cgi-bin/paper?S1600536808026457 |
| spellingShingle | Orhan Büyükgüngör Zerrin Heren Gökhan Kaştaş Hümeyra Paşaoğlu cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrate Acta Crystallographica Section E |
| title | cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrate |
| title_full | cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrate |
| title_fullStr | cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrate |
| title_full_unstemmed | cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrate |
| title_short | cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2N,N′]copper(II) pentahydrate |
| title_sort | cis bis butylamine 954 n bis sulfadiazine 1 8722 954 2n n 8242 copper ii pentahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808026457 |
| work_keys_str_mv | AT orhanb252y252kg252ng246r cisbisbutylamine954nbissulfadiazine187229542nn8242copperiipentahydrate AT zerrinheren cisbisbutylamine954nbissulfadiazine187229542nn8242copperiipentahydrate AT g246khanka351ta351 cisbisbutylamine954nbissulfadiazine187229542nn8242copperiipentahydrate AT h252meyrapa351ao287lu cisbisbutylamine954nbissulfadiazine187229542nn8242copperiipentahydrate |