High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing process

An important aspect of energy conservation and emission reduction in automotive industry is to improve the combustion efficiency of gasoline. The full combustion of gasoline will inevitably cause an increase in exhaust temperature. The coarsening and dissolution behavior of precipitates in steel wil...

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Main Authors: Jiahao Zheng, Yang Zhao, Liqing Chen
Format: Article
Language:English
Published: Elsevier 2023-09-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785423017179
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author Jiahao Zheng
Yang Zhao
Liqing Chen
author_facet Jiahao Zheng
Yang Zhao
Liqing Chen
author_sort Jiahao Zheng
collection DOAJ
description An important aspect of energy conservation and emission reduction in automotive industry is to improve the combustion efficiency of gasoline. The full combustion of gasoline will inevitably cause an increase in exhaust temperature. The coarsening and dissolution behavior of precipitates in steel will lead to a decrease in its high-temperature mechanical properties when the engine is used for a long time in such an alternating heating and cooling environment. In order to obtain ferritic stainless steel with good high-temperature resistance, this paper is based on 444 ferritic stainless steel and attempts to partially replace Mo element with W element to obtain Laves phase containing W, Mo, and Nb with more stable high-temperature performance. A simulated cyclic high-temperature annealing process up to 1050 °C was designed to investigate the precipitation behavior in this modified ferritic stainless steel. The results show that using W to replace Mo in 444 ferritic stainless steel can refine the grains of ferritic stainless steel. It can not only provide better solid solution strengthening at elevated temperature, but also stabilize the Laves phase and provide precipitation strengthening. The reason is that the W elements can change the composition of the Laves phase in ferritic stainless steels and precipitate Fe2(Nb, W) with high thermal stability to provide stable precipitation strengthening during long-term alternating annealing. The W-rich Laves phase is prone to precipitation at grain boundaries, effectively pinning grain boundaries and preventing microcracks from propagating along grain boundaries during service, thereby improving the service life of the steel.
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spelling doaj.art-6f3bd9f578ee408288ed18e83be244022023-10-30T06:02:41ZengElsevierJournal of Materials Research and Technology2238-78542023-09-012617121722High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing processJiahao Zheng0Yang Zhao1Liqing Chen2State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, ChinaSchool of Materials Science and Engineering, Northeastern University, Shenyang 110819, ChinaState Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, China; Corresponding author.An important aspect of energy conservation and emission reduction in automotive industry is to improve the combustion efficiency of gasoline. The full combustion of gasoline will inevitably cause an increase in exhaust temperature. The coarsening and dissolution behavior of precipitates in steel will lead to a decrease in its high-temperature mechanical properties when the engine is used for a long time in such an alternating heating and cooling environment. In order to obtain ferritic stainless steel with good high-temperature resistance, this paper is based on 444 ferritic stainless steel and attempts to partially replace Mo element with W element to obtain Laves phase containing W, Mo, and Nb with more stable high-temperature performance. A simulated cyclic high-temperature annealing process up to 1050 °C was designed to investigate the precipitation behavior in this modified ferritic stainless steel. The results show that using W to replace Mo in 444 ferritic stainless steel can refine the grains of ferritic stainless steel. It can not only provide better solid solution strengthening at elevated temperature, but also stabilize the Laves phase and provide precipitation strengthening. The reason is that the W elements can change the composition of the Laves phase in ferritic stainless steels and precipitate Fe2(Nb, W) with high thermal stability to provide stable precipitation strengthening during long-term alternating annealing. The W-rich Laves phase is prone to precipitation at grain boundaries, effectively pinning grain boundaries and preventing microcracks from propagating along grain boundaries during service, thereby improving the service life of the steel.http://www.sciencedirect.com/science/article/pii/S2238785423017179Ferritic stainless steelPrecipitation behaviorTungstenLaves phaseCyclic annealing
spellingShingle Jiahao Zheng
Yang Zhao
Liqing Chen
High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing process
Journal of Materials Research and Technology
Ferritic stainless steel
Precipitation behavior
Tungsten
Laves phase
Cyclic annealing
title High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing process
title_full High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing process
title_fullStr High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing process
title_full_unstemmed High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing process
title_short High-temperature precipitation behavior of W-containing 444-type ferritic stainless steel in a simulated cyclic annealing process
title_sort high temperature precipitation behavior of w containing 444 type ferritic stainless steel in a simulated cyclic annealing process
topic Ferritic stainless steel
Precipitation behavior
Tungsten
Laves phase
Cyclic annealing
url http://www.sciencedirect.com/science/article/pii/S2238785423017179
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AT yangzhao hightemperatureprecipitationbehaviorofwcontaining444typeferriticstainlesssteelinasimulatedcyclicannealingprocess
AT liqingchen hightemperatureprecipitationbehaviorofwcontaining444typeferriticstainlesssteelinasimulatedcyclicannealingprocess