Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as Dispersant

Limestone is commonly used for wall painting, but it is easy to be dirty. In this study, a self-cleaning limestone paint was synthesized by modifying dispersant and TiO2 nanoparticles. The TiO2 that prepared by TiCl3 were functionalized with PEG6000 as a surface activating agent. The paint achieved...

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Main Authors: Nur Fadhilah, Niki Etruly, Maktum Muharja, Dyah Sawitri
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2017-12-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
Subjects:
Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/800
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author Nur Fadhilah
Niki Etruly
Maktum Muharja
Dyah Sawitri
author_facet Nur Fadhilah
Niki Etruly
Maktum Muharja
Dyah Sawitri
author_sort Nur Fadhilah
collection DOAJ
description Limestone is commonly used for wall painting, but it is easy to be dirty. In this study, a self-cleaning limestone paint was synthesized by modifying dispersant and TiO2 nanoparticles. The TiO2 that prepared by TiCl3 were functionalized with PEG6000 as a surface activating agent. The paint achieved highest impurity degradation of 83.11 % for the mass ratio of TiO2 and PEG6000 (MRTP) of 1: 6, in which TiO2 average size distribution was 75.81 µm2, the particle surface area of TiO2 was 2,544 µm2, and the smallest contact angle was 7°. It was found that the dispersant (PEG6000) significantly improved the self-cleaning ability of limestone paint. The surface tension reduction from PEG6000-modified prevented the agglomeration process of TiO2 and suggests that the limestone paint a good self-cleaning coating for wall painting.
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spelling doaj.art-6fb0f6641fab4902a30b338e3ae2f9c62023-09-22T03:48:12ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932017-12-0112335135610.9767/bcrec.12.3.800.351-356912Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as DispersantNur Fadhilah0Niki Etruly1Maktum Muharja2Dyah Sawitri3Engineering Physics Department, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaEngineering Physics Department, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaChemical Engineering Department, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaEngineering Physics Department, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaLimestone is commonly used for wall painting, but it is easy to be dirty. In this study, a self-cleaning limestone paint was synthesized by modifying dispersant and TiO2 nanoparticles. The TiO2 that prepared by TiCl3 were functionalized with PEG6000 as a surface activating agent. The paint achieved highest impurity degradation of 83.11 % for the mass ratio of TiO2 and PEG6000 (MRTP) of 1: 6, in which TiO2 average size distribution was 75.81 µm2, the particle surface area of TiO2 was 2,544 µm2, and the smallest contact angle was 7°. It was found that the dispersant (PEG6000) significantly improved the self-cleaning ability of limestone paint. The surface tension reduction from PEG6000-modified prevented the agglomeration process of TiO2 and suggests that the limestone paint a good self-cleaning coating for wall painting.https://journal.bcrec.id/index.php/bcrec/article/view/800tio2 photocatalystpeg6000 dispersantlimestoneself cleaning
spellingShingle Nur Fadhilah
Niki Etruly
Maktum Muharja
Dyah Sawitri
Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as Dispersant
Bulletin of Chemical Reaction Engineering & Catalysis
tio2 photocatalyst
peg6000 dispersant
limestone
self cleaning
title Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as Dispersant
title_full Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as Dispersant
title_fullStr Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as Dispersant
title_full_unstemmed Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as Dispersant
title_short Self-Cleaning Limestone Paint Modified by Nanoparticles TiO2 Synthesized from TiCl3 as Precursors and PEG6000 as Dispersant
title_sort self cleaning limestone paint modified by nanoparticles tio2 synthesized from ticl3 as precursors and peg6000 as dispersant
topic tio2 photocatalyst
peg6000 dispersant
limestone
self cleaning
url https://journal.bcrec.id/index.php/bcrec/article/view/800
work_keys_str_mv AT nurfadhilah selfcleaninglimestonepaintmodifiedbynanoparticlestio2synthesizedfromticl3asprecursorsandpeg6000asdispersant
AT nikietruly selfcleaninglimestonepaintmodifiedbynanoparticlestio2synthesizedfromticl3asprecursorsandpeg6000asdispersant
AT maktummuharja selfcleaninglimestonepaintmodifiedbynanoparticlestio2synthesizedfromticl3asprecursorsandpeg6000asdispersant
AT dyahsawitri selfcleaninglimestonepaintmodifiedbynanoparticlestio2synthesizedfromticl3asprecursorsandpeg6000asdispersant