A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen

A novel and green method of olefin epoxidation was developed by using aqueous hydrogen peroxide as the terminal oxidation agent over Co-Fe3O4 magnetic nanoparticles catalyst in acetonitrile medium. This process showed excellent conversion and selectivity toward both terminal and substituted olefins....

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Main Authors: Jiangfeng Huang, Yingting Wang, Zheng Hao, Xinhua Peng
Format: Article
Language:English
Published: Elsevier 2017-11-01
Series:Journal of Saudi Chemical Society
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610315001465
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author Jiangfeng Huang
Yingting Wang
Zheng Hao
Xinhua Peng
author_facet Jiangfeng Huang
Yingting Wang
Zheng Hao
Xinhua Peng
author_sort Jiangfeng Huang
collection DOAJ
description A novel and green method of olefin epoxidation was developed by using aqueous hydrogen peroxide as the terminal oxidation agent over Co-Fe3O4 magnetic nanoparticles catalyst in acetonitrile medium. This process showed excellent conversion and selectivity toward both terminal and substituted olefins. Co-Fe3O4 magnetic nanoparticles could be recycled and reused without significant loss of catalytic activity in this transformation.
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spelling doaj.art-6fc5ac5de09e49e69b488a4d6c1e56572022-12-21T18:03:49ZengElsevierJournal of Saudi Chemical Society1319-61032017-11-0121781181610.1016/j.jscs.2015.12.005A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogenJiangfeng HuangYingting WangZheng HaoXinhua PengA novel and green method of olefin epoxidation was developed by using aqueous hydrogen peroxide as the terminal oxidation agent over Co-Fe3O4 magnetic nanoparticles catalyst in acetonitrile medium. This process showed excellent conversion and selectivity toward both terminal and substituted olefins. Co-Fe3O4 magnetic nanoparticles could be recycled and reused without significant loss of catalytic activity in this transformation.http://www.sciencedirect.com/science/article/pii/S1319610315001465Co-Fe3O4Hydrogen peroxideEpoxidationOlefins
spellingShingle Jiangfeng Huang
Yingting Wang
Zheng Hao
Xinhua Peng
A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen
Journal of Saudi Chemical Society
Co-Fe3O4
Hydrogen peroxide
Epoxidation
Olefins
title A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen
title_full A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen
title_fullStr A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen
title_full_unstemmed A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen
title_short A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen
title_sort recyclable fe3o4 supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen
topic Co-Fe3O4
Hydrogen peroxide
Epoxidation
Olefins
url http://www.sciencedirect.com/science/article/pii/S1319610315001465
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