The Mechanism of Alkali Metal Ion Sorption by Iron(III) Phosphate
Alkali metal ion exchange (Li + , Na + and K + ) on iron(III) phosphate (FePO 4 ) was studied potentiometrically as a function of temperature and metal ion concentration. The uptake behaviour of iron(III) phosphate was inferred from a comparison of the K + ions sorbed and the loss of H + ions from t...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
1999-10-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749901700903 |
| _version_ | 1797288038325288960 |
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| author | S. Mustafa A. Naeem S.U. Nisa S. Murtaza M. Khalid |
| author_facet | S. Mustafa A. Naeem S.U. Nisa S. Murtaza M. Khalid |
| author_sort | S. Mustafa |
| collection | DOAJ |
| description | Alkali metal ion exchange (Li + , Na + and K + ) on iron(III) phosphate (FePO 4 ) was studied potentiometrically as a function of temperature and metal ion concentration. The uptake behaviour of iron(III) phosphate was inferred from a comparison of the K + ions sorbed and the loss of H + ions from the exchanger. FT-IR spectroscopic studies and dissolution studies of FePO 4 confirmed the uptake mechanism of alkali metal cations as cation exchange. The potentiometric titration data were employed to evaluate the apparent dissociation constants of iron(III) phosphate which were found to depend on the temperature of the system. The corresponding thermodynamic parameters ΔH 0 and ΔS 0 were also evaluated. |
| first_indexed | 2024-03-07T18:43:30Z |
| format | Article |
| id | doaj.art-6fc7c92c6a3f4613b94cfd375972c70c |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T18:43:30Z |
| publishDate | 1999-10-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-6fc7c92c6a3f4613b94cfd375972c70c2024-03-02T03:16:02ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381999-10-011710.1177/026361749901700903The Mechanism of Alkali Metal Ion Sorption by Iron(III) PhosphateS. MustafaA. NaeemS.U. NisaS. MurtazaM. KhalidAlkali metal ion exchange (Li + , Na + and K + ) on iron(III) phosphate (FePO 4 ) was studied potentiometrically as a function of temperature and metal ion concentration. The uptake behaviour of iron(III) phosphate was inferred from a comparison of the K + ions sorbed and the loss of H + ions from the exchanger. FT-IR spectroscopic studies and dissolution studies of FePO 4 confirmed the uptake mechanism of alkali metal cations as cation exchange. The potentiometric titration data were employed to evaluate the apparent dissociation constants of iron(III) phosphate which were found to depend on the temperature of the system. The corresponding thermodynamic parameters ΔH 0 and ΔS 0 were also evaluated.https://doi.org/10.1177/026361749901700903 |
| spellingShingle | S. Mustafa A. Naeem S.U. Nisa S. Murtaza M. Khalid The Mechanism of Alkali Metal Ion Sorption by Iron(III) Phosphate Adsorption Science & Technology |
| title | The Mechanism of Alkali Metal Ion Sorption by Iron(III) Phosphate |
| title_full | The Mechanism of Alkali Metal Ion Sorption by Iron(III) Phosphate |
| title_fullStr | The Mechanism of Alkali Metal Ion Sorption by Iron(III) Phosphate |
| title_full_unstemmed | The Mechanism of Alkali Metal Ion Sorption by Iron(III) Phosphate |
| title_short | The Mechanism of Alkali Metal Ion Sorption by Iron(III) Phosphate |
| title_sort | mechanism of alkali metal ion sorption by iron iii phosphate |
| url | https://doi.org/10.1177/026361749901700903 |
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