3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate)
This work addresses the formation and the internal morphology of polyelectrolyte layers obtained by the layer-by-layer method. A multimodal characterization showed the absence of stratification of the films formed by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Beilstein-Institut
2016-02-01
|
| Series: | Beilstein Journal of Nanotechnology |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjnano.7.18 |
| _version_ | 1811264639798870016 |
|---|---|
| author | Eduardo Guzmán Armando Maestro Sara Llamas Jesús Álvarez-Rodríguez Francisco Ortega Ángel Maroto-Valiente Ramón G. Rubio |
| author_facet | Eduardo Guzmán Armando Maestro Sara Llamas Jesús Álvarez-Rodríguez Francisco Ortega Ángel Maroto-Valiente Ramón G. Rubio |
| author_sort | Eduardo Guzmán |
| collection | DOAJ |
| description | This work addresses the formation and the internal morphology of polyelectrolyte layers obtained by the layer-by-layer method. A multimodal characterization showed the absence of stratification of the films formed by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate). Indeed the final organization might be regarded as three-dimensional solid-supported inter-polyelectrolyte films. The growth mechanism of the multilayers, followed using a quartz crystal microbalance, evidences two different growth trends, which show a dependency on the ionic strength due to its influence onto the polymer conformation. The hydration state does not modify the multilayer growth, but it contributes to the total adsorbed mass of the film. The water associated with the polyelectrolyte films leads to their swelling and plastification. The use of X-ray photoelectron spectroscopy has allowed for deeper insights on the internal structure and composition of the polyelectrolyte multilayers. |
| first_indexed | 2024-04-12T20:08:06Z |
| format | Article |
| id | doaj.art-6fefa49fedf342b8b9143b4b8da0955e |
| institution | Directory Open Access Journal |
| issn | 2190-4286 |
| language | English |
| last_indexed | 2024-04-12T20:08:06Z |
| publishDate | 2016-02-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Nanotechnology |
| spelling | doaj.art-6fefa49fedf342b8b9143b4b8da0955e2022-12-22T03:18:20ZengBeilstein-InstitutBeilstein Journal of Nanotechnology2190-42862016-02-017119720810.3762/bjnano.7.182190-4286-7-183D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate)Eduardo Guzmán0Armando Maestro1Sara Llamas2Jesús Álvarez-Rodríguez3Francisco Ortega4Ángel Maroto-Valiente5Ramón G. Rubio6Departamento de Química Física I-Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040 Madrid, SpainDepartment of Physics - Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, CB3 0HE Cambridge, United KingdomIstituto per l’Energetica e le Interfasi - U.O.S. Genova, Consiglio Nazionale delle Ricerche, Via De Marini 6, 16149 Genova, ItalyDepartamento de Química Inorgánica y Química Técnica - Facultad de Ciencias Universidad Nacional de Educación a Distancia, C/ Senda del Rey 9, 28040 MadridDepartamento de Química Física I-Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040 Madrid, SpainDepartamento de Química Inorgánica y Química Técnica - Facultad de Ciencias Universidad Nacional de Educación a Distancia, C/ Senda del Rey 9, 28040 MadridDepartamento de Química Física I-Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040 Madrid, SpainThis work addresses the formation and the internal morphology of polyelectrolyte layers obtained by the layer-by-layer method. A multimodal characterization showed the absence of stratification of the films formed by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate). Indeed the final organization might be regarded as three-dimensional solid-supported inter-polyelectrolyte films. The growth mechanism of the multilayers, followed using a quartz crystal microbalance, evidences two different growth trends, which show a dependency on the ionic strength due to its influence onto the polymer conformation. The hydration state does not modify the multilayer growth, but it contributes to the total adsorbed mass of the film. The water associated with the polyelectrolyte films leads to their swelling and plastification. The use of X-ray photoelectron spectroscopy has allowed for deeper insights on the internal structure and composition of the polyelectrolyte multilayers.https://doi.org/10.3762/bjnano.7.18charge compensationhydrationpolyelectrolyte multilayersstratificationswelling |
| spellingShingle | Eduardo Guzmán Armando Maestro Sara Llamas Jesús Álvarez-Rodríguez Francisco Ortega Ángel Maroto-Valiente Ramón G. Rubio 3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate) Beilstein Journal of Nanotechnology charge compensation hydration polyelectrolyte multilayers stratification swelling |
| title | 3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate) |
| title_full | 3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate) |
| title_fullStr | 3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate) |
| title_full_unstemmed | 3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate) |
| title_short | 3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate) |
| title_sort | 3d solid supported inter polyelectrolyte complexes obtained by the alternate deposition of poly diallyldimethylammonium chloride and poly sodium 4 styrenesulfonate |
| topic | charge compensation hydration polyelectrolyte multilayers stratification swelling |
| url | https://doi.org/10.3762/bjnano.7.18 |
| work_keys_str_mv | AT eduardoguzman 3dsolidsupportedinterpolyelectrolytecomplexesobtainedbythealternatedepositionofpolydiallyldimethylammoniumchlorideandpolysodium4styrenesulfonate AT armandomaestro 3dsolidsupportedinterpolyelectrolytecomplexesobtainedbythealternatedepositionofpolydiallyldimethylammoniumchlorideandpolysodium4styrenesulfonate AT sarallamas 3dsolidsupportedinterpolyelectrolytecomplexesobtainedbythealternatedepositionofpolydiallyldimethylammoniumchlorideandpolysodium4styrenesulfonate AT jesusalvarezrodriguez 3dsolidsupportedinterpolyelectrolytecomplexesobtainedbythealternatedepositionofpolydiallyldimethylammoniumchlorideandpolysodium4styrenesulfonate AT franciscoortega 3dsolidsupportedinterpolyelectrolytecomplexesobtainedbythealternatedepositionofpolydiallyldimethylammoniumchlorideandpolysodium4styrenesulfonate AT angelmarotovaliente 3dsolidsupportedinterpolyelectrolytecomplexesobtainedbythealternatedepositionofpolydiallyldimethylammoniumchlorideandpolysodium4styrenesulfonate AT ramongrubio 3dsolidsupportedinterpolyelectrolytecomplexesobtainedbythealternatedepositionofpolydiallyldimethylammoniumchlorideandpolysodium4styrenesulfonate |