trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II)
In the centrosymmetric title complex, [Ni(C7H6NO2)2(H2O)2], the NiII atom, located on an inversion center, is six-coordinated in a distorted octahedral geometry defined by two N and four O atoms from the two chelating 2-(2-pyridyl)acetate ligands and two aqua ligands. The molecules form a three-dime...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
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International Union of Crystallography
2010-09-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810030904 |
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author | Hong Zhou Lei Zhao Rong Huang Hao-Liang Li |
author_facet | Hong Zhou Lei Zhao Rong Huang Hao-Liang Li |
author_sort | Hong Zhou |
collection | DOAJ |
description | In the centrosymmetric title complex, [Ni(C7H6NO2)2(H2O)2], the NiII atom, located on an inversion center, is six-coordinated in a distorted octahedral geometry defined by two N and four O atoms from the two chelating 2-(2-pyridyl)acetate ligands and two aqua ligands. The molecules form a three-dimensional framework by O—H...O hydrogen bonds and aromatic π–π stacking interactions, with a centroid–centroid distance of 3.506 (3) Å. |
first_indexed | 2024-12-24T00:32:22Z |
format | Article |
id | doaj.art-700dfac223d34a3d90b9d2d790867d02 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-24T00:32:22Z |
publishDate | 2010-09-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-700dfac223d34a3d90b9d2d790867d022022-12-21T17:24:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1068m106810.1107/S1600536810030904trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II)Hong ZhouLei ZhaoRong HuangHao-Liang LiIn the centrosymmetric title complex, [Ni(C7H6NO2)2(H2O)2], the NiII atom, located on an inversion center, is six-coordinated in a distorted octahedral geometry defined by two N and four O atoms from the two chelating 2-(2-pyridyl)acetate ligands and two aqua ligands. The molecules form a three-dimensional framework by O—H...O hydrogen bonds and aromatic π–π stacking interactions, with a centroid–centroid distance of 3.506 (3) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536810030904 |
spellingShingle | Hong Zhou Lei Zhao Rong Huang Hao-Liang Li trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II) Acta Crystallographica Section E |
title | trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II) |
title_full | trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II) |
title_fullStr | trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II) |
title_full_unstemmed | trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II) |
title_short | trans-Diaquabis[2-(2-pyridyl)acetato-κ2N,O]nickel(II) |
title_sort | trans diaquabis 2 2 pyridyl acetato amp 954 2n o nickel ii |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536810030904 |
work_keys_str_mv | AT hongzhou transdiaquabis22pyridylacetatoamp9542nonickelii AT leizhao transdiaquabis22pyridylacetatoamp9542nonickelii AT ronghuang transdiaquabis22pyridylacetatoamp9542nonickelii AT haoliangli transdiaquabis22pyridylacetatoamp9542nonickelii |