Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique

Recent advances in the controlled RAFT polymerization of complex macromolecular architectures based on poly(N-vinyl pyrrolidone), PNVP, are summarized in this review article. Special interest is given to the synthesis of statistical copolymers, block copolymers, and star polymers and copolymers, alo...

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Main Authors: Nikoletta Roka, Olga Kokkorogianni, Philippos Kontoes-Georgoudakis, Ioannis Choinopoulos, Marinos Pitsikalis
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/4/701
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author Nikoletta Roka
Olga Kokkorogianni
Philippos Kontoes-Georgoudakis
Ioannis Choinopoulos
Marinos Pitsikalis
author_facet Nikoletta Roka
Olga Kokkorogianni
Philippos Kontoes-Georgoudakis
Ioannis Choinopoulos
Marinos Pitsikalis
author_sort Nikoletta Roka
collection DOAJ
description Recent advances in the controlled RAFT polymerization of complex macromolecular architectures based on poly(N-vinyl pyrrolidone), PNVP, are summarized in this review article. Special interest is given to the synthesis of statistical copolymers, block copolymers, and star polymers and copolymers, along with graft copolymers and more complex architectures. In all cases, PNVP is produced via RAFT techniques, whereas other polymerization methods can be employed in combination with RAFT to provide the desired final products. The advantages and limitations of the synthetic methodologies are discussed in detail.
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spelling doaj.art-703575a836a140e38546b56fba57f2052023-11-23T21:44:27ZengMDPI AGPolymers2073-43602022-02-0114470110.3390/polym14040701Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization TechniqueNikoletta Roka0Olga Kokkorogianni1Philippos Kontoes-Georgoudakis2Ioannis Choinopoulos3Marinos Pitsikalis4Industrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, GreeceIndustrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, GreeceIndustrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, GreeceIndustrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, GreeceIndustrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, GreeceRecent advances in the controlled RAFT polymerization of complex macromolecular architectures based on poly(N-vinyl pyrrolidone), PNVP, are summarized in this review article. Special interest is given to the synthesis of statistical copolymers, block copolymers, and star polymers and copolymers, along with graft copolymers and more complex architectures. In all cases, PNVP is produced via RAFT techniques, whereas other polymerization methods can be employed in combination with RAFT to provide the desired final products. The advantages and limitations of the synthetic methodologies are discussed in detail.https://www.mdpi.com/2073-4360/14/4/701poly(N-vinyl pyrrolidone)RAFT polymerizationstatistical copolymersblock copolymersstar polymersgraft copolymers
spellingShingle Nikoletta Roka
Olga Kokkorogianni
Philippos Kontoes-Georgoudakis
Ioannis Choinopoulos
Marinos Pitsikalis
Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
Polymers
poly(N-vinyl pyrrolidone)
RAFT polymerization
statistical copolymers
block copolymers
star polymers
graft copolymers
title Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
title_full Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
title_fullStr Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
title_full_unstemmed Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
title_short Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
title_sort recent advances in the synthesis of complex macromolecular architectures based on poly n vinyl pyrrolidone and the raft polymerization technique
topic poly(N-vinyl pyrrolidone)
RAFT polymerization
statistical copolymers
block copolymers
star polymers
graft copolymers
url https://www.mdpi.com/2073-4360/14/4/701
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