Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials
The synthesis of nontoxic plasticizers derived from the waste residues of the rosin-processing industry can reduce pollution and promote the high-value utilization of the waste residues of rosin. In this study, four kinds of sustainable branched plasticizers derived from a biomass resource, eugenol...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2022-12-01
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| Series: | Arabian Journal of Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1878535222006475 |
| _version_ | 1811209958779256832 |
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| author | Yun Hu Jing Zhou Yufeng Ma Yu Bei Feilong Hu Zhimin Kou Yonghong Zhou Puyou Jia |
| author_facet | Yun Hu Jing Zhou Yufeng Ma Yu Bei Feilong Hu Zhimin Kou Yonghong Zhou Puyou Jia |
| author_sort | Yun Hu |
| collection | DOAJ |
| description | The synthesis of nontoxic plasticizers derived from the waste residues of the rosin-processing industry can reduce pollution and promote the high-value utilization of the waste residues of rosin. In this study, four kinds of sustainable branched plasticizers derived from a biomass resource, eugenol (derived from the waste residues of the rosin processing industry), were synthesized via one-pot solvent free polymerization and used to plasticize polyvinyl chloride (PVC). Internally plasticized PVC was fabricated using thiolated DPE (branched plasticizers based on eugenol). The thermal stability, tensile properties, microstructure, volatility behavior, and solvent extraction resistance of plasticized PVC were investigated. Compared with the behavior of the commercial plasticizer dioctyl phthalate, the thermal stability, plasticizing efficiency, and migration resistance of the branched plasticizers are superior. The acute oral toxicity dose of each branched plasticizer was extremely high at 5000 mg/kg of body weight, with no deaths among test animals. Compared with externally plasticized PVC, the internally plasticized PVC showed zero weight loss in volatility and leaching tests despite its less effective plasticization. All the branched plasticizers have potential application in plastic products. |
| first_indexed | 2024-04-12T04:48:03Z |
| format | Article |
| id | doaj.art-704447b0721e4cc394ab7912fdda8051 |
| institution | Directory Open Access Journal |
| issn | 1878-5352 |
| language | English |
| last_indexed | 2024-04-12T04:48:03Z |
| publishDate | 2022-12-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Arabian Journal of Chemistry |
| spelling | doaj.art-704447b0721e4cc394ab7912fdda80512022-12-22T03:47:24ZengElsevierArabian Journal of Chemistry1878-53522022-12-011512104331Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materialsYun Hu0Jing Zhou1Yufeng Ma2Yu Bei3Feilong Hu4Zhimin Kou5Yonghong Zhou6Puyou Jia7Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), Jiangsu Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, ChinaWeifang Vocational College, School of Chemical Engineering, 06588 Haian Road, Weifang 262737, Shandong, ChinaCollege of Materials Science and Engineering, Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, 159 Longpan Road, Nanjing 210037, ChinaCollege of Materials Science and Engineering, Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, 159 Longpan Road, Nanjing 210037, China; College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, ChinaKey Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi Minzu University, Nanning 530006, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), Jiangsu Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, China; College of Materials Science and Engineering, Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, 159 Longpan Road, Nanjing 210037, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), Jiangsu Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, China; College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, ChinaInstitute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), Jiangsu Key Lab of Biomass Energy and Materials, Jiangsu Province, 16 Suojin North Road, Nanjing 210042, China; Corresponding author.The synthesis of nontoxic plasticizers derived from the waste residues of the rosin-processing industry can reduce pollution and promote the high-value utilization of the waste residues of rosin. In this study, four kinds of sustainable branched plasticizers derived from a biomass resource, eugenol (derived from the waste residues of the rosin processing industry), were synthesized via one-pot solvent free polymerization and used to plasticize polyvinyl chloride (PVC). Internally plasticized PVC was fabricated using thiolated DPE (branched plasticizers based on eugenol). The thermal stability, tensile properties, microstructure, volatility behavior, and solvent extraction resistance of plasticized PVC were investigated. Compared with the behavior of the commercial plasticizer dioctyl phthalate, the thermal stability, plasticizing efficiency, and migration resistance of the branched plasticizers are superior. The acute oral toxicity dose of each branched plasticizer was extremely high at 5000 mg/kg of body weight, with no deaths among test animals. Compared with externally plasticized PVC, the internally plasticized PVC showed zero weight loss in volatility and leaching tests despite its less effective plasticization. All the branched plasticizers have potential application in plastic products.http://www.sciencedirect.com/science/article/pii/S1878535222006475Waste residues of the rosin processing industryEugenolSustainable plasticizerGreen polymerization |
| spellingShingle | Yun Hu Jing Zhou Yufeng Ma Yu Bei Feilong Hu Zhimin Kou Yonghong Zhou Puyou Jia Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials Arabian Journal of Chemistry Waste residues of the rosin processing industry Eugenol Sustainable plasticizer Green polymerization |
| title | Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials |
| title_full | Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials |
| title_fullStr | Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials |
| title_full_unstemmed | Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials |
| title_short | Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials |
| title_sort | branched plasticizers derived from eugenol via green polymerization for low non migration and externally internally plasticized polyvinyl chloride materials |
| topic | Waste residues of the rosin processing industry Eugenol Sustainable plasticizer Green polymerization |
| url | http://www.sciencedirect.com/science/article/pii/S1878535222006475 |
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