Anion effect controlling the selectivity in the zinc-catalysed copolymerisation of CO2 and cyclohexene oxide

Anion effect controlling the selectivity in the zinc-catalysed copolymerisation of CO2 and cyclohexene oxide

The choice of the anion has a surprisingly strong effect on the incorporation of CO2 into the polymer obtained during the zinc-catalysed copolymerisation of CO2 and cyclohexene oxide. The product span ranges from polyethercarbonates, where short polyether sequences alternate with carbonate linkages,...

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Bibliographic Details
Main Authors: Sait Elmas, Muhammad Afzal Subhani, Walter Leitner, Thomas E. Müller
Format: Article
Language:English
Published: Beilstein-Institut 2015-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
anion effect
carbon dioxide
CO2 chemistry
copolymerisation
polyethercarbonate
zinc catalyst
Online Access:https://doi.org/10.3762/bjoc.11.7

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