Chemical and electrochemical dissolution of chromium at room and elevated temperatures

The influence of temperature on electrochemical and chemical dissolution of chromium was studied in the acidic sulphuric solutions. The hydrogen evolution reaction, as well as the anodic dissolution and chemical dissolution of chromium from activated surfaces in sulphuric acid solutions pH 1 follow...

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Main Authors: Jegdić Bore, Stevanović Maja, Jegdić Aleksandar
Format: Article
Language:English
Published: Mining and Metallurgy Institute, Bor 2015-01-01
Series:Mining and Metallurgy Engineering Bor
Subjects:
Online Access:https://scindeks-clanci.ceon.rs/data/pdf/2334-8836/2015/2334-88361502149J.pdf
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author Jegdić Bore
Stevanović Maja
Jegdić Aleksandar
author_facet Jegdić Bore
Stevanović Maja
Jegdić Aleksandar
author_sort Jegdić Bore
collection DOAJ
description The influence of temperature on electrochemical and chemical dissolution of chromium was studied in the acidic sulphuric solutions. The hydrogen evolution reaction, as well as the anodic dissolution and chemical dissolution of chromium from activated surfaces in sulphuric acid solutions pH 1 follow the Arrhenius law, with the apparent activation energies of 35 kJ mol-1, 58 kJ mol-1 and 62 kJ mol-1, respectively. The higher activation energy of the chemical dissolution of chromium leads to the signifycantly noticeable chemical corrosion on elevated temperatures in comparison with the electrochemical corrosion.
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spelling doaj.art-7064d5e43c644d90958fc1ed1500cf752024-04-03T09:36:16ZengMining and Metallurgy Institute, BorMining and Metallurgy Engineering Bor2334-88362406-13952015-01-012015214916010.5937/MMEB1502149J2334-88361502149JChemical and electrochemical dissolution of chromium at room and elevated temperaturesJegdić Bore0https://orcid.org/0000-0002-3287-3653Stevanović Maja1https://orcid.org/0000-0002-0383-3935Jegdić Aleksandar2NU Institut za hemiju tehnologiju i metalurgiju, IHTM, Beograd, SerbiaNU Institut za hemiju tehnologiju i metalurgiju, IHTM, Beograd, SerbiaNU Institut za hemiju tehnologiju i metalurgiju, IHTM, Beograd, SerbiaThe influence of temperature on electrochemical and chemical dissolution of chromium was studied in the acidic sulphuric solutions. The hydrogen evolution reaction, as well as the anodic dissolution and chemical dissolution of chromium from activated surfaces in sulphuric acid solutions pH 1 follow the Arrhenius law, with the apparent activation energies of 35 kJ mol-1, 58 kJ mol-1 and 62 kJ mol-1, respectively. The higher activation energy of the chemical dissolution of chromium leads to the signifycantly noticeable chemical corrosion on elevated temperatures in comparison with the electrochemical corrosion.https://scindeks-clanci.ceon.rs/data/pdf/2334-8836/2015/2334-88361502149J.pdfchromium chemical corrosionelectrochemical dissolutionactivation energy
spellingShingle Jegdić Bore
Stevanović Maja
Jegdić Aleksandar
Chemical and electrochemical dissolution of chromium at room and elevated temperatures
Mining and Metallurgy Engineering Bor
chromium chemical corrosion
electrochemical dissolution
activation energy
title Chemical and electrochemical dissolution of chromium at room and elevated temperatures
title_full Chemical and electrochemical dissolution of chromium at room and elevated temperatures
title_fullStr Chemical and electrochemical dissolution of chromium at room and elevated temperatures
title_full_unstemmed Chemical and electrochemical dissolution of chromium at room and elevated temperatures
title_short Chemical and electrochemical dissolution of chromium at room and elevated temperatures
title_sort chemical and electrochemical dissolution of chromium at room and elevated temperatures
topic chromium chemical corrosion
electrochemical dissolution
activation energy
url https://scindeks-clanci.ceon.rs/data/pdf/2334-8836/2015/2334-88361502149J.pdf
work_keys_str_mv AT jegdicbore chemicalandelectrochemicaldissolutionofchromiumatroomandelevatedtemperatures
AT stevanovicmaja chemicalandelectrochemicaldissolutionofchromiumatroomandelevatedtemperatures
AT jegdicaleksandar chemicalandelectrochemicaldissolutionofchromiumatroomandelevatedtemperatures