Chemical and electrochemical dissolution of chromium at room and elevated temperatures
The influence of temperature on electrochemical and chemical dissolution of chromium was studied in the acidic sulphuric solutions. The hydrogen evolution reaction, as well as the anodic dissolution and chemical dissolution of chromium from activated surfaces in sulphuric acid solutions pH 1 follow...
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Format: | Article |
Language: | English |
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Mining and Metallurgy Institute, Bor
2015-01-01
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Series: | Mining and Metallurgy Engineering Bor |
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Online Access: | https://scindeks-clanci.ceon.rs/data/pdf/2334-8836/2015/2334-88361502149J.pdf |
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author | Jegdić Bore Stevanović Maja Jegdić Aleksandar |
author_facet | Jegdić Bore Stevanović Maja Jegdić Aleksandar |
author_sort | Jegdić Bore |
collection | DOAJ |
description | The influence of temperature on electrochemical and chemical dissolution of chromium was studied in the acidic sulphuric solutions. The hydrogen evolution reaction, as well as the anodic dissolution and chemical dissolution of chromium from activated surfaces in sulphuric acid solutions pH 1 follow the Arrhenius law, with the apparent activation energies of 35 kJ mol-1, 58 kJ mol-1 and 62 kJ mol-1, respectively. The higher activation energy of the chemical dissolution of chromium leads to the signifycantly noticeable chemical corrosion on elevated temperatures in comparison with the electrochemical corrosion. |
first_indexed | 2024-04-24T14:09:46Z |
format | Article |
id | doaj.art-7064d5e43c644d90958fc1ed1500cf75 |
institution | Directory Open Access Journal |
issn | 2334-8836 2406-1395 |
language | English |
last_indexed | 2024-04-24T14:09:46Z |
publishDate | 2015-01-01 |
publisher | Mining and Metallurgy Institute, Bor |
record_format | Article |
series | Mining and Metallurgy Engineering Bor |
spelling | doaj.art-7064d5e43c644d90958fc1ed1500cf752024-04-03T09:36:16ZengMining and Metallurgy Institute, BorMining and Metallurgy Engineering Bor2334-88362406-13952015-01-012015214916010.5937/MMEB1502149J2334-88361502149JChemical and electrochemical dissolution of chromium at room and elevated temperaturesJegdić Bore0https://orcid.org/0000-0002-3287-3653Stevanović Maja1https://orcid.org/0000-0002-0383-3935Jegdić Aleksandar2NU Institut za hemiju tehnologiju i metalurgiju, IHTM, Beograd, SerbiaNU Institut za hemiju tehnologiju i metalurgiju, IHTM, Beograd, SerbiaNU Institut za hemiju tehnologiju i metalurgiju, IHTM, Beograd, SerbiaThe influence of temperature on electrochemical and chemical dissolution of chromium was studied in the acidic sulphuric solutions. The hydrogen evolution reaction, as well as the anodic dissolution and chemical dissolution of chromium from activated surfaces in sulphuric acid solutions pH 1 follow the Arrhenius law, with the apparent activation energies of 35 kJ mol-1, 58 kJ mol-1 and 62 kJ mol-1, respectively. The higher activation energy of the chemical dissolution of chromium leads to the signifycantly noticeable chemical corrosion on elevated temperatures in comparison with the electrochemical corrosion.https://scindeks-clanci.ceon.rs/data/pdf/2334-8836/2015/2334-88361502149J.pdfchromium chemical corrosionelectrochemical dissolutionactivation energy |
spellingShingle | Jegdić Bore Stevanović Maja Jegdić Aleksandar Chemical and electrochemical dissolution of chromium at room and elevated temperatures Mining and Metallurgy Engineering Bor chromium chemical corrosion electrochemical dissolution activation energy |
title | Chemical and electrochemical dissolution of chromium at room and elevated temperatures |
title_full | Chemical and electrochemical dissolution of chromium at room and elevated temperatures |
title_fullStr | Chemical and electrochemical dissolution of chromium at room and elevated temperatures |
title_full_unstemmed | Chemical and electrochemical dissolution of chromium at room and elevated temperatures |
title_short | Chemical and electrochemical dissolution of chromium at room and elevated temperatures |
title_sort | chemical and electrochemical dissolution of chromium at room and elevated temperatures |
topic | chromium chemical corrosion electrochemical dissolution activation energy |
url | https://scindeks-clanci.ceon.rs/data/pdf/2334-8836/2015/2334-88361502149J.pdf |
work_keys_str_mv | AT jegdicbore chemicalandelectrochemicaldissolutionofchromiumatroomandelevatedtemperatures AT stevanovicmaja chemicalandelectrochemicaldissolutionofchromiumatroomandelevatedtemperatures AT jegdicaleksandar chemicalandelectrochemicaldissolutionofchromiumatroomandelevatedtemperatures |