Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell Fillers

An effective model to calculate thermal conductivity of polymer composites using core-shell fillers is presented, wherein a core material of filler grains is covered by a layer of a high-thermal-conductivity (HTC) material. Such fillers can provide a significant increase of the composite thermal con...

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Main Authors: Jan Czyzewski, Andrzej Rybak, Karolina Gaska, Robert Sekula, Czeslaw Kapusta
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/23/5480
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author Jan Czyzewski
Andrzej Rybak
Karolina Gaska
Robert Sekula
Czeslaw Kapusta
author_facet Jan Czyzewski
Andrzej Rybak
Karolina Gaska
Robert Sekula
Czeslaw Kapusta
author_sort Jan Czyzewski
collection DOAJ
description An effective model to calculate thermal conductivity of polymer composites using core-shell fillers is presented, wherein a core material of filler grains is covered by a layer of a high-thermal-conductivity (HTC) material. Such fillers can provide a significant increase of the composite thermal conductivity by an addition of a small amount of the HTC material. The model employs the Lewis-Nielsen formula describing filled systems. The effective thermal conductivity of the core-shell filler grains is calculated using the Russel model for porous materials. Modelling results are compared with recent measurements made on composites filled with cellulose microbeads coated with hexagonal boron nitride (h-BN) platelets and good agreement is demonstrated. Comparison with measurements made on epoxy composites, using silver-coated glass spheres as a filler, is also provided. It is demonstrated how the modelling procedure can improve understanding of properties of materials and structures used and mechanisms of thermal conduction within the composite.
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spelling doaj.art-706bdede14ca4326a0339653b17c00de2023-11-20T23:09:47ZengMDPI AGMaterials1996-19442020-12-011323548010.3390/ma13235480Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell FillersJan Czyzewski0Andrzej Rybak1Karolina Gaska2Robert Sekula3Czeslaw Kapusta4Hitachi ABB Power Grids Research, 31-154 Krakow, PolandABB Corporate Technology Center, 31-038 Krakow, PolandDepartment of Solid State Physics, Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, 30-059 Krakow, PolandHitachi ABB Power Grids Research, 31-154 Krakow, PolandDepartment of Solid State Physics, Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, 30-059 Krakow, PolandAn effective model to calculate thermal conductivity of polymer composites using core-shell fillers is presented, wherein a core material of filler grains is covered by a layer of a high-thermal-conductivity (HTC) material. Such fillers can provide a significant increase of the composite thermal conductivity by an addition of a small amount of the HTC material. The model employs the Lewis-Nielsen formula describing filled systems. The effective thermal conductivity of the core-shell filler grains is calculated using the Russel model for porous materials. Modelling results are compared with recent measurements made on composites filled with cellulose microbeads coated with hexagonal boron nitride (h-BN) platelets and good agreement is demonstrated. Comparison with measurements made on epoxy composites, using silver-coated glass spheres as a filler, is also provided. It is demonstrated how the modelling procedure can improve understanding of properties of materials and structures used and mechanisms of thermal conduction within the composite.https://www.mdpi.com/1996-1944/13/23/5480polymer-matrix compositeepoxy resinfilled epoxycore-shell fillerthermal propertieseffective thermal conductivity
spellingShingle Jan Czyzewski
Andrzej Rybak
Karolina Gaska
Robert Sekula
Czeslaw Kapusta
Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell Fillers
Materials
polymer-matrix composite
epoxy resin
filled epoxy
core-shell filler
thermal properties
effective thermal conductivity
title Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell Fillers
title_full Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell Fillers
title_fullStr Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell Fillers
title_full_unstemmed Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell Fillers
title_short Modelling of Effective Thermal Conductivity of Composites Filled with Core-Shell Fillers
title_sort modelling of effective thermal conductivity of composites filled with core shell fillers
topic polymer-matrix composite
epoxy resin
filled epoxy
core-shell filler
thermal properties
effective thermal conductivity
url https://www.mdpi.com/1996-1944/13/23/5480
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