Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track Cables

The interface of multi-layer insulation is a relatively weak point in the cable system during the long-term high-temperature service. Space charge is prone to continuously accumulate in the interface area, leading to the deterioration of electrical properties and even insulation failure in advance....

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Main Authors: Zhichao Qiao, Wangsong Wu, Zhaowei Wang, Ling Zhang, Yuanxiang Zhou
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/11/2162
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author Zhichao Qiao
Wangsong Wu
Zhaowei Wang
Ling Zhang
Yuanxiang Zhou
author_facet Zhichao Qiao
Wangsong Wu
Zhaowei Wang
Ling Zhang
Yuanxiang Zhou
author_sort Zhichao Qiao
collection DOAJ
description The interface of multi-layer insulation is a relatively weak point in the cable system during the long-term high-temperature service. Space charge is prone to continuously accumulate in the interface area, leading to the deterioration of electrical properties and even insulation failure in advance. The knowledge about thermal oxidation of polyethylene (PE) materials at the molecular level is still urgent to explore. Herein, single-layer and double-layer PE insulation, representing the typical insulation structure of frequency-shift pulse voltage track cables, were prepared and thermally aged in the oven for up to 360 h. Thermal, mechanical, electrical, and space charge characterizations were systematically carried out. Thermogravimetric analyzer and oxidation induced temperature (OIT) measurements confirmed that LDPE’s thermal-oxidative aging temperature range was the lowest among the three PE groups in the O<sub>2</sub> atmosphere. After 360 h thermal aging, the tensile property of HDPE material kept relatively stable, while the elongation at break of the other two groups was lower than 50%. Unaged HDPE exhibits apparent charge injection and migration, leading to the severe electric field distortion of 20%. Noticeable charge accumulation can be observed at the unaged double-layer sample interface due to the mismatching of DC conductivity, which play a significant role in the aged double-layer samples. This work utilizes precise thermal analysis to provide new information about the resistance ability of thermal oxidation of LDPE, FPE, and HDPE, and its influence on space charge behaviors, which is helpful for the insulation design and evaluation in cable applications.
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spelling doaj.art-708b72f32d22494f87ff4b862792b28b2023-11-23T14:40:42ZengMDPI AGPolymers2073-43602022-05-011411216210.3390/polym14112162Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track CablesZhichao Qiao0Wangsong Wu1Zhaowei Wang2Ling Zhang3Yuanxiang Zhou4CRSC Research and Design Institute Group Co., Ltd., Beijing 100070, ChinaState Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University, Beijing 100084, ChinaWuwei Electric Power Supply Company of the State Grid, Wuwei 733000, ChinaState Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University, Beijing 100084, ChinaState Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University, Beijing 100084, ChinaThe interface of multi-layer insulation is a relatively weak point in the cable system during the long-term high-temperature service. Space charge is prone to continuously accumulate in the interface area, leading to the deterioration of electrical properties and even insulation failure in advance. The knowledge about thermal oxidation of polyethylene (PE) materials at the molecular level is still urgent to explore. Herein, single-layer and double-layer PE insulation, representing the typical insulation structure of frequency-shift pulse voltage track cables, were prepared and thermally aged in the oven for up to 360 h. Thermal, mechanical, electrical, and space charge characterizations were systematically carried out. Thermogravimetric analyzer and oxidation induced temperature (OIT) measurements confirmed that LDPE’s thermal-oxidative aging temperature range was the lowest among the three PE groups in the O<sub>2</sub> atmosphere. After 360 h thermal aging, the tensile property of HDPE material kept relatively stable, while the elongation at break of the other two groups was lower than 50%. Unaged HDPE exhibits apparent charge injection and migration, leading to the severe electric field distortion of 20%. Noticeable charge accumulation can be observed at the unaged double-layer sample interface due to the mismatching of DC conductivity, which play a significant role in the aged double-layer samples. This work utilizes precise thermal analysis to provide new information about the resistance ability of thermal oxidation of LDPE, FPE, and HDPE, and its influence on space charge behaviors, which is helpful for the insulation design and evaluation in cable applications.https://www.mdpi.com/2073-4360/14/11/2162multi-layer insulationpolyethylenespace chargethermal agingtensile strengthoxidation induced temperature
spellingShingle Zhichao Qiao
Wangsong Wu
Zhaowei Wang
Ling Zhang
Yuanxiang Zhou
Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track Cables
Polymers
multi-layer insulation
polyethylene
space charge
thermal aging
tensile strength
oxidation induced temperature
title Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track Cables
title_full Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track Cables
title_fullStr Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track Cables
title_full_unstemmed Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track Cables
title_short Space Charge Behavior of Thermally Aged Polyethylene Insulation of Track Cables
title_sort space charge behavior of thermally aged polyethylene insulation of track cables
topic multi-layer insulation
polyethylene
space charge
thermal aging
tensile strength
oxidation induced temperature
url https://www.mdpi.com/2073-4360/14/11/2162
work_keys_str_mv AT zhichaoqiao spacechargebehaviorofthermallyagedpolyethyleneinsulationoftrackcables
AT wangsongwu spacechargebehaviorofthermallyagedpolyethyleneinsulationoftrackcables
AT zhaoweiwang spacechargebehaviorofthermallyagedpolyethyleneinsulationoftrackcables
AT lingzhang spacechargebehaviorofthermallyagedpolyethyleneinsulationoftrackcables
AT yuanxiangzhou spacechargebehaviorofthermallyagedpolyethyleneinsulationoftrackcables