Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under Compression
This report presents ‘giant’ and long-range premelting effects appearing in dielectric properties for the temperature and pressure paths of studies, with an explicit critical-like portrayal. The result was obtained for the ‘classic’ low molecular weight compound: nitrobenzene, tested in the solid an...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-02-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/13/2/247 |
| _version_ | 1797621573869371392 |
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| author | Jakub Kalabiński Aleksandra Drozd-Rzoska Sylwester J. Rzoska |
| author_facet | Jakub Kalabiński Aleksandra Drozd-Rzoska Sylwester J. Rzoska |
| author_sort | Jakub Kalabiński |
| collection | DOAJ |
| description | This report presents ‘giant’ and long-range premelting effects appearing in dielectric properties for the temperature and pressure paths of studies, with an explicit critical-like portrayal. The result was obtained for the ‘classic’ low molecular weight compound: nitrobenzene, tested in the solid and liquid phases. Dielectric studies enable the ‘extraction’ of the response from liquid layers between crystalline grains. Compressing increased the premelting effects, probably due to the ‘crushing’ of crystalline grains by isotropic squeezing and increasing the liquid layers between grains. This report indicates the significance of considering the melting/freezing phenomenon from the point of view of the ‘solid crystalline grains and critical-type liquid layers in synergic interactions’ concept. |
| first_indexed | 2024-03-11T08:57:55Z |
| format | Article |
| id | doaj.art-70c1f0df19c041acafb20fb7cc3b0614 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-11T08:57:55Z |
| publishDate | 2023-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-70c1f0df19c041acafb20fb7cc3b06142023-11-16T19:55:32ZengMDPI AGCrystals2073-43522023-02-0113224710.3390/cryst13020247Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under CompressionJakub Kalabiński0Aleksandra Drozd-Rzoska1Sylwester J. Rzoska2Institute of High Pressure Physics Polish Academy of Science, ul. Sokołowska 29/37, 01-142 Warsaw, PolandInstitute of High Pressure Physics Polish Academy of Science, ul. Sokołowska 29/37, 01-142 Warsaw, PolandInstitute of High Pressure Physics Polish Academy of Science, ul. Sokołowska 29/37, 01-142 Warsaw, PolandThis report presents ‘giant’ and long-range premelting effects appearing in dielectric properties for the temperature and pressure paths of studies, with an explicit critical-like portrayal. The result was obtained for the ‘classic’ low molecular weight compound: nitrobenzene, tested in the solid and liquid phases. Dielectric studies enable the ‘extraction’ of the response from liquid layers between crystalline grains. Compressing increased the premelting effects, probably due to the ‘crushing’ of crystalline grains by isotropic squeezing and increasing the liquid layers between grains. This report indicates the significance of considering the melting/freezing phenomenon from the point of view of the ‘solid crystalline grains and critical-type liquid layers in synergic interactions’ concept.https://www.mdpi.com/2073-4352/13/2/247premelting effectsdielectric spectroscopyhigh pressures |
| spellingShingle | Jakub Kalabiński Aleksandra Drozd-Rzoska Sylwester J. Rzoska Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under Compression Crystals premelting effects dielectric spectroscopy high pressures |
| title | Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under Compression |
| title_full | Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under Compression |
| title_fullStr | Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under Compression |
| title_full_unstemmed | Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under Compression |
| title_short | Giant Premelting Effects for Solid–Liquid Discontinuous Transition in Nitrobenzene under Compression |
| title_sort | giant premelting effects for solid liquid discontinuous transition in nitrobenzene under compression |
| topic | premelting effects dielectric spectroscopy high pressures |
| url | https://www.mdpi.com/2073-4352/13/2/247 |
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