Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction Temperatures

Hydrothermal carbonization (HTC) has been proved to be a promising technology for swine manure (SM) treatment. Currently, there is a lack of systematic understanding of the transformation characteristics of nutrient speciation in the HTC of SM. In this study, the speciation of the main nutrients (N/...

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Main Authors: Jiangbo Xiong, Shuaiwei Chen, Jiaxin Wang, Yujie Wang, Xiaolin Fang, Huajun Huang
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/15/4114
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author Jiangbo Xiong
Shuaiwei Chen
Jiaxin Wang
Yujie Wang
Xiaolin Fang
Huajun Huang
author_facet Jiangbo Xiong
Shuaiwei Chen
Jiaxin Wang
Yujie Wang
Xiaolin Fang
Huajun Huang
author_sort Jiangbo Xiong
collection DOAJ
description Hydrothermal carbonization (HTC) has been proved to be a promising technology for swine manure (SM) treatment. Currently, there is a lack of systematic understanding of the transformation characteristics of nutrient speciation in the HTC of SM. In this study, the speciation of the main nutrients (N/P/K) in SM-derived hydrochar produced at different reaction temperatures (200–280 °C) was investigated. The recovery of P (61.0–67.1%) in hydrochars was significantly higher than that of N (23.0–39.8%) and K (25.5–30.0%), and the increase in reaction temperature promoted the recovery of P and reduced the recovery of N. After the HTC treatment, the percentage of soluble/available P was reduced from 61.6% in raw SM to 4.0–23.9% in hydrochars, while that of moderately labile/slow-release P was improved from 29.2% in raw SM feedstock to 65.5–82.7%. An obvious reduction was also found in the amounts of available N (from 51.3% in raw SM feedstock to 33.0–40.5% in hydrochars). The percentages of slow-release N and residual N in hydrochars produced at 240 °C reached the maximum and minimum values (46.4% and 18.9%), respectively. A total of 49.5–58.3% of K retained in hydrochars was residual (invalid) potassium. From the perspective of the mobility and availability of N, P and K only, it was suggested that the HTC of SM should be carried out at 220–240 °C. Compared with the original SM, it is safer and more effective to use the SM-derived hydrochar as an organic fertilizer.
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spelling doaj.art-70d83a185c394b81a6a29606999921822023-11-22T05:51:55ZengMDPI AGMaterials1996-19442021-07-011415411410.3390/ma14154114Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction TemperaturesJiangbo Xiong0Shuaiwei Chen1Jiaxin Wang2Yujie Wang3Xiaolin Fang4Huajun Huang5School of Land Resources and Environment, Key Laboratory of Agricultural Resource and Ecology in the Poyang Lake Basin of Jiangxi Province, Jiangxi Agricultural University, Nanchang 330045, ChinaSchool of Forestry, Fujian Agriculture and Forestry University, Fuzhou 350002, ChinaSchool of Land Resources and Environment, Key Laboratory of Agricultural Resource and Ecology in the Poyang Lake Basin of Jiangxi Province, Jiangxi Agricultural University, Nanchang 330045, ChinaSchool of Land Resources and Environment, Key Laboratory of Agricultural Resource and Ecology in the Poyang Lake Basin of Jiangxi Province, Jiangxi Agricultural University, Nanchang 330045, ChinaSchool of Land Resources and Environment, Key Laboratory of Agricultural Resource and Ecology in the Poyang Lake Basin of Jiangxi Province, Jiangxi Agricultural University, Nanchang 330045, ChinaSchool of Land Resources and Environment, Key Laboratory of Agricultural Resource and Ecology in the Poyang Lake Basin of Jiangxi Province, Jiangxi Agricultural University, Nanchang 330045, ChinaHydrothermal carbonization (HTC) has been proved to be a promising technology for swine manure (SM) treatment. Currently, there is a lack of systematic understanding of the transformation characteristics of nutrient speciation in the HTC of SM. In this study, the speciation of the main nutrients (N/P/K) in SM-derived hydrochar produced at different reaction temperatures (200–280 °C) was investigated. The recovery of P (61.0–67.1%) in hydrochars was significantly higher than that of N (23.0–39.8%) and K (25.5–30.0%), and the increase in reaction temperature promoted the recovery of P and reduced the recovery of N. After the HTC treatment, the percentage of soluble/available P was reduced from 61.6% in raw SM to 4.0–23.9% in hydrochars, while that of moderately labile/slow-release P was improved from 29.2% in raw SM feedstock to 65.5–82.7%. An obvious reduction was also found in the amounts of available N (from 51.3% in raw SM feedstock to 33.0–40.5% in hydrochars). The percentages of slow-release N and residual N in hydrochars produced at 240 °C reached the maximum and minimum values (46.4% and 18.9%), respectively. A total of 49.5–58.3% of K retained in hydrochars was residual (invalid) potassium. From the perspective of the mobility and availability of N, P and K only, it was suggested that the HTC of SM should be carried out at 220–240 °C. Compared with the original SM, it is safer and more effective to use the SM-derived hydrochar as an organic fertilizer.https://www.mdpi.com/1996-1944/14/15/4114swine manurehydrothermal carbonizationhydrocharnutrientsspeciation
spellingShingle Jiangbo Xiong
Shuaiwei Chen
Jiaxin Wang
Yujie Wang
Xiaolin Fang
Huajun Huang
Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction Temperatures
Materials
swine manure
hydrothermal carbonization
hydrochar
nutrients
speciation
title Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction Temperatures
title_full Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction Temperatures
title_fullStr Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction Temperatures
title_full_unstemmed Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction Temperatures
title_short Speciation of Main Nutrients (N/P/K) in Hydrochars Produced from the Hydrothermal Carbonization of Swine Manure under Different Reaction Temperatures
title_sort speciation of main nutrients n p k in hydrochars produced from the hydrothermal carbonization of swine manure under different reaction temperatures
topic swine manure
hydrothermal carbonization
hydrochar
nutrients
speciation
url https://www.mdpi.com/1996-1944/14/15/4114
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