Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion
In this study, we synthesized a gallol-functionalized PSA and generated micropatterns on its surface to improve its underwater adhesion. Compared to the adhesive-substrate interactions of benzyl and phenol-functionalized PSAs in water, Gallol PSA exhibited greater interactions with the substrate. Fu...
Main Authors: | , , , , , , |
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Format: | Article |
Language: | English |
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Elsevier
2023-12-01
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Series: | Materials & Design |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S0264127523009218 |
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author | Seong-Ju Lee Jong-Ho Back Ji-Soo Kim Mo-Beom Yi Gi-Yeon Han Young Do Kim Hyun-Joong Kim |
author_facet | Seong-Ju Lee Jong-Ho Back Ji-Soo Kim Mo-Beom Yi Gi-Yeon Han Young Do Kim Hyun-Joong Kim |
author_sort | Seong-Ju Lee |
collection | DOAJ |
description | In this study, we synthesized a gallol-functionalized PSA and generated micropatterns on its surface to improve its underwater adhesion. Compared to the adhesive-substrate interactions of benzyl and phenol-functionalized PSAs in water, Gallol PSA exhibited greater interactions with the substrate. Furthermore, the micropattern on the PSA surface provided a drainage channel for water during the bonding process so that water is not trapped at the substrate-adhesive interface. Moreover, the drainage channel allows the formation of small and uniform adhesion defects, which minimize the deterioration in adhesion caused by water. And the adhesive manufacturing process is also simple, without any gallol protection and deprotection steps, and can be achieved using the current adhesive industry infrastructure. This facile fabrication strategy and its adhesive properties could promote the commercialization of gallol-functionalized PSAs with underwater adhesion. |
first_indexed | 2024-03-08T23:39:41Z |
format | Article |
id | doaj.art-70f909e85b42495ca3169f823e1b8795 |
institution | Directory Open Access Journal |
issn | 0264-1275 |
language | English |
last_indexed | 2024-03-08T23:39:41Z |
publishDate | 2023-12-01 |
publisher | Elsevier |
record_format | Article |
series | Materials & Design |
spelling | doaj.art-70f909e85b42495ca3169f823e1b87952023-12-14T05:20:30ZengElsevierMaterials & Design0264-12752023-12-01236112505Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesionSeong-Ju Lee0Jong-Ho Back1Ji-Soo Kim2Mo-Beom Yi3Gi-Yeon Han4Young Do Kim5Hyun-Joong Kim6Department of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of Korea; Research Institute of Agriculture and Life Sciences, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaSamsung Display Co., Ltd., Cheonan, 31086, Republic of Korea; Corresponding authors.Department of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of Korea; Research Institute of Agriculture and Life Sciences, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of Korea; Corresponding authors.In this study, we synthesized a gallol-functionalized PSA and generated micropatterns on its surface to improve its underwater adhesion. Compared to the adhesive-substrate interactions of benzyl and phenol-functionalized PSAs in water, Gallol PSA exhibited greater interactions with the substrate. Furthermore, the micropattern on the PSA surface provided a drainage channel for water during the bonding process so that water is not trapped at the substrate-adhesive interface. Moreover, the drainage channel allows the formation of small and uniform adhesion defects, which minimize the deterioration in adhesion caused by water. And the adhesive manufacturing process is also simple, without any gallol protection and deprotection steps, and can be achieved using the current adhesive industry infrastructure. This facile fabrication strategy and its adhesive properties could promote the commercialization of gallol-functionalized PSAs with underwater adhesion.http://www.sciencedirect.com/science/article/pii/S0264127523009218AdhesivesBio-inspiredPolymersPressure-sensitive adhesivesGallolMicrostructures |
spellingShingle | Seong-Ju Lee Jong-Ho Back Ji-Soo Kim Mo-Beom Yi Gi-Yeon Han Young Do Kim Hyun-Joong Kim Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion Materials & Design Adhesives Bio-inspired Polymers Pressure-sensitive adhesives Gallol Microstructures |
title | Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion |
title_full | Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion |
title_fullStr | Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion |
title_full_unstemmed | Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion |
title_short | Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion |
title_sort | surface patterned gallol pressure sensitive adhesives for strong underwater adhesion |
topic | Adhesives Bio-inspired Polymers Pressure-sensitive adhesives Gallol Microstructures |
url | http://www.sciencedirect.com/science/article/pii/S0264127523009218 |
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