Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion

In this study, we synthesized a gallol-functionalized PSA and generated micropatterns on its surface to improve its underwater adhesion. Compared to the adhesive-substrate interactions of benzyl and phenol-functionalized PSAs in water, Gallol PSA exhibited greater interactions with the substrate. Fu...

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Main Authors: Seong-Ju Lee, Jong-Ho Back, Ji-Soo Kim, Mo-Beom Yi, Gi-Yeon Han, Young Do Kim, Hyun-Joong Kim
Format: Article
Language:English
Published: Elsevier 2023-12-01
Series:Materials & Design
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127523009218
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author Seong-Ju Lee
Jong-Ho Back
Ji-Soo Kim
Mo-Beom Yi
Gi-Yeon Han
Young Do Kim
Hyun-Joong Kim
author_facet Seong-Ju Lee
Jong-Ho Back
Ji-Soo Kim
Mo-Beom Yi
Gi-Yeon Han
Young Do Kim
Hyun-Joong Kim
author_sort Seong-Ju Lee
collection DOAJ
description In this study, we synthesized a gallol-functionalized PSA and generated micropatterns on its surface to improve its underwater adhesion. Compared to the adhesive-substrate interactions of benzyl and phenol-functionalized PSAs in water, Gallol PSA exhibited greater interactions with the substrate. Furthermore, the micropattern on the PSA surface provided a drainage channel for water during the bonding process so that water is not trapped at the substrate-adhesive interface. Moreover, the drainage channel allows the formation of small and uniform adhesion defects, which minimize the deterioration in adhesion caused by water. And the adhesive manufacturing process is also simple, without any gallol protection and deprotection steps, and can be achieved using the current adhesive industry infrastructure. This facile fabrication strategy and its adhesive properties could promote the commercialization of gallol-functionalized PSAs with underwater adhesion.
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spelling doaj.art-70f909e85b42495ca3169f823e1b87952023-12-14T05:20:30ZengElsevierMaterials & Design0264-12752023-12-01236112505Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesionSeong-Ju Lee0Jong-Ho Back1Ji-Soo Kim2Mo-Beom Yi3Gi-Yeon Han4Young Do Kim5Hyun-Joong Kim6Department of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of Korea; Research Institute of Agriculture and Life Sciences, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaDepartment of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of KoreaSamsung Display Co., Ltd., Cheonan, 31086, Republic of Korea; Corresponding authors.Department of Agriculture, Forestry and Bioresources, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of Korea; Research Institute of Agriculture and Life Sciences, Seoul National University, Gwanak-ro 1, Gwanak-gu, Seoul, 08826, Republic of Korea; Corresponding authors.In this study, we synthesized a gallol-functionalized PSA and generated micropatterns on its surface to improve its underwater adhesion. Compared to the adhesive-substrate interactions of benzyl and phenol-functionalized PSAs in water, Gallol PSA exhibited greater interactions with the substrate. Furthermore, the micropattern on the PSA surface provided a drainage channel for water during the bonding process so that water is not trapped at the substrate-adhesive interface. Moreover, the drainage channel allows the formation of small and uniform adhesion defects, which minimize the deterioration in adhesion caused by water. And the adhesive manufacturing process is also simple, without any gallol protection and deprotection steps, and can be achieved using the current adhesive industry infrastructure. This facile fabrication strategy and its adhesive properties could promote the commercialization of gallol-functionalized PSAs with underwater adhesion.http://www.sciencedirect.com/science/article/pii/S0264127523009218AdhesivesBio-inspiredPolymersPressure-sensitive adhesivesGallolMicrostructures
spellingShingle Seong-Ju Lee
Jong-Ho Back
Ji-Soo Kim
Mo-Beom Yi
Gi-Yeon Han
Young Do Kim
Hyun-Joong Kim
Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion
Materials & Design
Adhesives
Bio-inspired
Polymers
Pressure-sensitive adhesives
Gallol
Microstructures
title Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion
title_full Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion
title_fullStr Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion
title_full_unstemmed Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion
title_short Surface-patterned gallol pressure-sensitive adhesives for strong underwater adhesion
title_sort surface patterned gallol pressure sensitive adhesives for strong underwater adhesion
topic Adhesives
Bio-inspired
Polymers
Pressure-sensitive adhesives
Gallol
Microstructures
url http://www.sciencedirect.com/science/article/pii/S0264127523009218
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