2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY
2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl and 2(Cy2NH2)2SO4. Sn(SO4)22Cy2NH2Cl complexes have been obtained on allowing Cy2NH2O2C-SO3H and Cy2NH2HSO4 to react respectively with SnBu2Cl2 and SnBu3Cl in specific ratios.The molecular structures of these compounds have been determined on the basis of the infrared d...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2014-01-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201301&vol=1&aid=3911 |
| _version_ | 1818236063546605568 |
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| author | DAOUDA NDOYE LIBASSE DIOP |
| author_facet | DAOUDA NDOYE LIBASSE DIOP |
| author_sort | DAOUDA NDOYE |
| collection | DOAJ |
| description | 2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl and 2(Cy2NH2)2SO4. Sn(SO4)22Cy2NH2Cl complexes have been obtained on allowing Cy2NH2O2C-SO3H and Cy2NH2HSO4 to react respectively with SnBu2Cl2 and SnBu3Cl in specific ratios.The molecular structures of these compounds have been determined on the basis of the infrared data. The suggested structures are dimeric, the tin atom being octacoordinated by four chelating sulfate anions, the monomeric basic entities being connected by hydrogen bonded cation chloride cation strings. |
| first_indexed | 2024-12-12T12:03:54Z |
| format | Article |
| id | doaj.art-70fe843ea38e40288b83003d1551d864 |
| institution | Directory Open Access Journal |
| issn | 1582-540X |
| language | English |
| last_indexed | 2024-12-12T12:03:54Z |
| publishDate | 2014-01-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj.art-70fe843ea38e40288b83003d1551d8642022-12-22T00:25:02ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2014-01-0114159622(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDYDAOUDA NDOYE0LIBASSE DIOP1Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, SénégalUniversité Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl and 2(Cy2NH2)2SO4. Sn(SO4)22Cy2NH2Cl complexes have been obtained on allowing Cy2NH2O2C-SO3H and Cy2NH2HSO4 to react respectively with SnBu2Cl2 and SnBu3Cl in specific ratios.The molecular structures of these compounds have been determined on the basis of the infrared data. The suggested structures are dimeric, the tin atom being octacoordinated by four chelating sulfate anions, the monomeric basic entities being connected by hydrogen bonded cation chloride cation strings.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201301&vol=1&aid=3911chelating sulfatedimerhexacoordinatedmonomeroctacoordinated |
| spellingShingle | DAOUDA NDOYE LIBASSE DIOP 2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry chelating sulfate dimer hexacoordinated monomer octacoordinated |
| title | 2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY |
| title_full | 2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY |
| title_fullStr | 2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY |
| title_full_unstemmed | 2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY |
| title_short | 2(Cy2NH2)2SO4Sn(SO4)2Cy2NH2Cl AND 2(Cy2NH2)2SO4Sn(SO4)22Cy2NH2Cl: SYNTHESIS AND INFRARED STUDY |
| title_sort | 2 cy2nh2 2so4sn so4 2cy2nh2cl and 2 cy2nh2 2so4sn so4 22cy2nh2cl synthesis and infrared study |
| topic | chelating sulfate dimer hexacoordinated monomer octacoordinated |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201301&vol=1&aid=3911 |
| work_keys_str_mv | AT daoudandoye 2cy2nh22so4snso42cy2nh2cland2cy2nh22so4snso422cy2nh2clsynthesisandinfraredstudy AT libassediop 2cy2nh22so4snso42cy2nh2cland2cy2nh22so4snso422cy2nh2clsynthesisandinfraredstudy |