Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical Approach

The Jurassic–Early Cretaceous was a time of variable organic carbon burial associated with fluctuations of marine primary productivity, weathering intensity, and redox conditions in the pore and bottom water at paleo-shelf areas in north Egypt. This time interval characterized the deposition of, fro...

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Main Authors: Ahmed Mansour, Thomas Gentzis, Ibrahim M. Ied, Mohamed S. Ahmed, Michael Wagreich
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/12/10/1213
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author Ahmed Mansour
Thomas Gentzis
Ibrahim M. Ied
Mohamed S. Ahmed
Michael Wagreich
author_facet Ahmed Mansour
Thomas Gentzis
Ibrahim M. Ied
Mohamed S. Ahmed
Michael Wagreich
author_sort Ahmed Mansour
collection DOAJ
description The Jurassic–Early Cretaceous was a time of variable organic carbon burial associated with fluctuations of marine primary productivity, weathering intensity, and redox conditions in the pore and bottom water at paleo-shelf areas in north Egypt. This time interval characterized the deposition of, from old to young, the Bahrein, Khatatba, Masajid, and Alam El Bueib Formations in the north Western Desert. Although several studies have been devoted to the excellent source rock units, such as the Khatatba and Alam El Bueib Formations, studies on paleoenvironmental changes in redox conditions, paleoproductivity, and continental weathering and their impact on organic carbon exports and their preservation for this interval are lacking. This study presents organic and inorganic geochemical data for the Jurassic–Lower Cretaceous sediments from the Almaz-1 well in the Shushan Basin, north Western Desert. A total of 32 cuttings samples were analyzed for their major and trace elements, carbonates, and total organic carbon (TOC) contents. Data allowed the reconstruction of paleoenvironmental conditions in the southern Tethys Ocean and assessment of the changes in paleo-redox, paleo-weathering, and marine primary productivity, and the role of sediment supply. Additionally, factors that governed the accumulation of organic matter in the sediment were interpreted. Results showed that the Khatatba Formation was deposited during a phase of enhanced marine primary productivity under prevalent anoxia, which triggered enhanced organic matter production and preservation. During the deposition of the Khatatba Formation, significant terrigenous sediment supply and continental weathering were followed by a limited contribution of coarse clastic sediment fluxes due to weak continental weathering and enhanced carbonate production. The Bahrein, Masajid, and Alam El Bueib Formations were deposited during low marine primary productivity and prevalent oxygenation conditions that led to poor organic matter production and preservation, respectively. A strong terrigenous sediment supply and continental weathering predominated during the deposition of the Bahrein Formation and the lower part of the Alam El Bueib Formation compared to the limited coarse clastic supply and continental weathering during the deposition of the carbonate Masajid Formation and the upper part of the Alam El Bueib Formation. Such conditions resulted in the enhanced dilution and decomposition of labile organic matter, and, thus, organic carbon-lean accumulation in these sediments.
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spelling doaj.art-71243cc4aabb46d2b331b522adbe24402023-11-24T01:28:51ZengMDPI AGMinerals2075-163X2022-09-011210121310.3390/min12101213Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical ApproachAhmed Mansour0Thomas Gentzis1Ibrahim M. Ied2Mohamed S. Ahmed3Michael Wagreich4Geology Department, Faculty of Science, Minia University, Minia 61519, EgyptCore Laboratories, 6316 Windfern Road, Houston, TX 77040, USAGeology Department, Faculty of Science, Zagazig University, Zagazig 44519, EgyptGeology and Geophysics Department, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Geology, Faculty of Earth Sciences, Geography and Astronomy, University of Vienna, 1090 Vienna, AustriaThe Jurassic–Early Cretaceous was a time of variable organic carbon burial associated with fluctuations of marine primary productivity, weathering intensity, and redox conditions in the pore and bottom water at paleo-shelf areas in north Egypt. This time interval characterized the deposition of, from old to young, the Bahrein, Khatatba, Masajid, and Alam El Bueib Formations in the north Western Desert. Although several studies have been devoted to the excellent source rock units, such as the Khatatba and Alam El Bueib Formations, studies on paleoenvironmental changes in redox conditions, paleoproductivity, and continental weathering and their impact on organic carbon exports and their preservation for this interval are lacking. This study presents organic and inorganic geochemical data for the Jurassic–Lower Cretaceous sediments from the Almaz-1 well in the Shushan Basin, north Western Desert. A total of 32 cuttings samples were analyzed for their major and trace elements, carbonates, and total organic carbon (TOC) contents. Data allowed the reconstruction of paleoenvironmental conditions in the southern Tethys Ocean and assessment of the changes in paleo-redox, paleo-weathering, and marine primary productivity, and the role of sediment supply. Additionally, factors that governed the accumulation of organic matter in the sediment were interpreted. Results showed that the Khatatba Formation was deposited during a phase of enhanced marine primary productivity under prevalent anoxia, which triggered enhanced organic matter production and preservation. During the deposition of the Khatatba Formation, significant terrigenous sediment supply and continental weathering were followed by a limited contribution of coarse clastic sediment fluxes due to weak continental weathering and enhanced carbonate production. The Bahrein, Masajid, and Alam El Bueib Formations were deposited during low marine primary productivity and prevalent oxygenation conditions that led to poor organic matter production and preservation, respectively. A strong terrigenous sediment supply and continental weathering predominated during the deposition of the Bahrein Formation and the lower part of the Alam El Bueib Formation compared to the limited coarse clastic supply and continental weathering during the deposition of the carbonate Masajid Formation and the upper part of the Alam El Bueib Formation. Such conditions resulted in the enhanced dilution and decomposition of labile organic matter, and, thus, organic carbon-lean accumulation in these sediments.https://www.mdpi.com/2075-163X/12/10/1213redox conditionsmarine primary productivitycontinental weathering intensityterrestrial clastic supplyorganic matter preservationcarbonate dilution
spellingShingle Ahmed Mansour
Thomas Gentzis
Ibrahim M. Ied
Mohamed S. Ahmed
Michael Wagreich
Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical Approach
Minerals
redox conditions
marine primary productivity
continental weathering intensity
terrestrial clastic supply
organic matter preservation
carbonate dilution
title Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical Approach
title_full Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical Approach
title_fullStr Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical Approach
title_full_unstemmed Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical Approach
title_short Paleoenvironmental Conditions and Factors Controlling Organic Carbon Accumulation during the Jurassic–Early Cretaceous, Egypt: Organic and Inorganic Geochemical Approach
title_sort paleoenvironmental conditions and factors controlling organic carbon accumulation during the jurassic early cretaceous egypt organic and inorganic geochemical approach
topic redox conditions
marine primary productivity
continental weathering intensity
terrestrial clastic supply
organic matter preservation
carbonate dilution
url https://www.mdpi.com/2075-163X/12/10/1213
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