Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene
In the cyclohexene ring of the title compound, C23H20BrNO3S, the –(CH2)4– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thiophene ring and th...
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| Format: | Article |
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International Union of Crystallography
2015-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015000195 |
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| author | Manpreet Kaur Jerry P. Jasinski H. S. Yathirajan Christopher Glidewell K. Byrappa |
| author_facet | Manpreet Kaur Jerry P. Jasinski H. S. Yathirajan Christopher Glidewell K. Byrappa |
| author_sort | Manpreet Kaur |
| collection | DOAJ |
| description | In the cyclohexene ring of the title compound, C23H20BrNO3S, the –(CH2)4– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thiophene ring and those of the benzene and phenyl rings are 35.2 (4) and 57.7 (3)°, respectively. The planes of the two aryl rings are twisted with respect to each other by 86.4 (6)°. In the molecule, there is an O—H...N hydrogen bond forming an S(6) ring motif. In the crystal, molecules are linked via C—H...O hydrogen bonds, forming chains parallel to [100]. |
| first_indexed | 2024-12-24T03:03:05Z |
| format | Article |
| id | doaj.art-712ac8d7b8c949d2a3d303ed7123f75f |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-24T03:03:05Z |
| publishDate | 2015-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-712ac8d7b8c949d2a3d303ed7123f75f2022-12-21T17:18:07ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-0171217617910.1107/S2056989015000195su5055Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiopheneManpreet Kaur0Jerry P. Jasinski1H. S. Yathirajan2Christopher Glidewell3K. Byrappa4Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, IndiaDepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USADepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, IndiaSchool of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, ScotlandMaterials Science Center, University of Mysore, Vijyana Bhavan Building, Manasagangotri, Mysore 570 006, IndiaIn the cyclohexene ring of the title compound, C23H20BrNO3S, the –(CH2)4– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thiophene ring and those of the benzene and phenyl rings are 35.2 (4) and 57.7 (3)°, respectively. The planes of the two aryl rings are twisted with respect to each other by 86.4 (6)°. In the molecule, there is an O—H...N hydrogen bond forming an S(6) ring motif. In the crystal, molecules are linked via C—H...O hydrogen bonds, forming chains parallel to [100].http://scripts.iucr.org/cgi-bin/paper?S2056989015000195crystal structure2-aminothiophene4,5,6,7-tetrahydrobenzo[b]thiopheneSchiff basehydrogen bonding |
| spellingShingle | Manpreet Kaur Jerry P. Jasinski H. S. Yathirajan Christopher Glidewell K. Byrappa Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene Acta Crystallographica Section E: Crystallographic Communications crystal structure 2-aminothiophene 4,5,6,7-tetrahydrobenzo[b]thiophene Schiff base hydrogen bonding |
| title | Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene |
| title_full | Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene |
| title_fullStr | Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene |
| title_full_unstemmed | Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene |
| title_short | Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene |
| title_sort | crystal structure of 3 benzoyl 2 5 bromo 2 hydroxy 3 methoxybenzylidene amino 4 5 6 7 tetrahydrobenzo b thiophene |
| topic | crystal structure 2-aminothiophene 4,5,6,7-tetrahydrobenzo[b]thiophene Schiff base hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015000195 |
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