Effect of Nitrogen Doping on the Optical Bandgap and Electrical Conductivity of Nitrogen-Doped Reduced Graphene Oxide

Graphene as a material for optoelectronic design applications has been significantly restricted owing to zero bandgap and non-compatible handling procedures compared with regular microelectronic ones. In this work, nitrogen-doped reduced graphene oxide (N-rGO) with tunable optical bandgap and enhanc...

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Bibliographic Details
Main Authors: Gunawan Witjaksono, Muhammad Junaid, Mohd Haris Khir, Zaka Ullah, Nelson Tansu, Mohamed Shuaib Bin Mohamed Saheed, Muhammad Aadil Siddiqui, Saeed S. Ba-Hashwan, Abdullah Saleh Algamili, Saeed Ahmed Magsi, Muhammad Zubair Aslam, Rab Nawaz
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/26/21/6424
Description
Summary:Graphene as a material for optoelectronic design applications has been significantly restricted owing to zero bandgap and non-compatible handling procedures compared with regular microelectronic ones. In this work, nitrogen-doped reduced graphene oxide (N-rGO) with tunable optical bandgap and enhanced electrical conductivity was synthesized via a microwave-assisted hydrothermal method. The properties of the synthesized N-rGO were determined using XPS, FTIR and Raman spectroscopy, UV/vis, as well as FESEM techniques. The UV/vis spectroscopic analysis confirmed the narrowness of the optical bandgap from 3.4 to 3.1, 2.5, and 2.2 eV in N-rGO samples, where N-rGO samples were synthesized with a nitrogen doping concentration of 2.80, 4.53, and 5.51 at.%. Besides, an enhanced n-type electrical conductivity in N-rGO was observed in Hall effect measurement. The observed tunable optoelectrical characteristics of N-rGO make it a suitable material for developing future optoelectronic devices at the nanoscale.
ISSN:1420-3049