EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICS

0.96(K0.49Na0.51)(Nb0.97Ta0.03)O₂-0.04Bi0.5Na0.5ZrO₃ + x mol% MnO₂ (0.96KNNT-0.04BNZ + x mol% MnO₂, x=0, 0.1, 0.2, 0.4, 0.6, 0.8) lead-free piezoelectric ceramics were prepared via conventional solid state method. The effect of MnO₂ doping content on the structure and electrical properties of 0.96K...

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Main Authors: Wenqin Luo, Zongyang Shen
Format: Article
Language:English
Published: University of Chemistry and Technology, Prague 2019-10-01
Series:Ceramics-Silikáty
Subjects:
Online Access: http://www.ceramics-silikaty.cz/index.php?page=cs_detail_doi&id=1282
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author Wenqin Luo
Zongyang Shen
author_facet Wenqin Luo
Zongyang Shen
author_sort Wenqin Luo
collection DOAJ
description 0.96(K0.49Na0.51)(Nb0.97Ta0.03)O₂-0.04Bi0.5Na0.5ZrO₃ + x mol% MnO₂ (0.96KNNT-0.04BNZ + x mol% MnO₂, x=0, 0.1, 0.2, 0.4, 0.6, 0.8) lead-free piezoelectric ceramics were prepared via conventional solid state method. The effect of MnO₂ doping content on the structure and electrical properties of 0.96KNNT-0.04BNZ ceramics was investigated. All samples had pure perovskite structure with coexistence of orthorhombic and tetragonal phases at room temperature. The 0.96KNNT-0.04BNZ + 0.2 mol% MnO₂ ceramic sample exhibited enhanced piezoelectric constant (d33=330 pC/N) and planar electromechanical coupling coefficient (kp=38.8%). In addition to other optimized electrical properties such as medium high dielectric permittivity (εT33/ ε₀ =1370) and mechanical quality factor (Qm=135), relatively low dielectric loss (tanδ=2.4%) and high Curie temperature (Tc=305 ̊C), this ceramic sample should be a promising lead-free alternative to toxic lead-based piezoelectric materials.
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spelling doaj.art-7145d5ec387f480fa460fb5afcbeb4232022-12-21T18:48:36ZengUniversity of Chemistry and Technology, PragueCeramics-Silikáty0862-54681804-58472019-10-0163439940210.13168/cs.2019.003610.13168/cs.2019.0036.20191104111856EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICSWenqin Luo0Zongyang Shen1 Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333403, China Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province, China National Light Industry Key Laboratory of Functional Ceramic Materials, School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333403, China 0.96(K0.49Na0.51)(Nb0.97Ta0.03)O₂-0.04Bi0.5Na0.5ZrO₃ + x mol% MnO₂ (0.96KNNT-0.04BNZ + x mol% MnO₂, x=0, 0.1, 0.2, 0.4, 0.6, 0.8) lead-free piezoelectric ceramics were prepared via conventional solid state method. The effect of MnO₂ doping content on the structure and electrical properties of 0.96KNNT-0.04BNZ ceramics was investigated. All samples had pure perovskite structure with coexistence of orthorhombic and tetragonal phases at room temperature. The 0.96KNNT-0.04BNZ + 0.2 mol% MnO₂ ceramic sample exhibited enhanced piezoelectric constant (d33=330 pC/N) and planar electromechanical coupling coefficient (kp=38.8%). In addition to other optimized electrical properties such as medium high dielectric permittivity (εT33/ ε₀ =1370) and mechanical quality factor (Qm=135), relatively low dielectric loss (tanδ=2.4%) and high Curie temperature (Tc=305 ̊C), this ceramic sample should be a promising lead-free alternative to toxic lead-based piezoelectric materials. http://www.ceramics-silikaty.cz/index.php?page=cs_detail_doi&id=1282 lead-free ceramics piezoelectric properties knn mno₂ doping
spellingShingle Wenqin Luo
Zongyang Shen
EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICS
Ceramics-Silikáty
lead-free ceramics
piezoelectric properties
knn
mno₂ doping
title EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICS
title_full EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICS
title_fullStr EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICS
title_full_unstemmed EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICS
title_short EFFECT OF MnO₂ ON THE ELECTRICAL PROPERTIES OF 0.96KNNT-0.04BNZ LEAD-FREE PIEZOELECTRIC CERAMICS
title_sort effect of mno₂ on the electrical properties of 0 96knnt 0 04bnz lead free piezoelectric ceramics
topic lead-free ceramics
piezoelectric properties
knn
mno₂ doping
url http://www.ceramics-silikaty.cz/index.php?page=cs_detail_doi&id=1282
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